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Article: Highly diastereoselective epoxidation of allyl-substituted cycloalkenes catalyzed by metalloporphyrins

TitleHighly diastereoselective epoxidation of allyl-substituted cycloalkenes catalyzed by metalloporphyrins
Authors
Chan, WKLiu, PYu, WYWong, MKChe, CM
Issue Date2004
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/orlef7/index.html
Citation
Organic Letters, 2004, v. 6 n. 10, p. 1597-1599 How to Cite?
DOI: http://dx.doi.org/10.1021/ol0496475
AbstractHighly diastereoselective epoxidations of allyl-substituted cycloalkenes including allylic alcohols, esters, and amines using sterically bulky metalloporphyrins [Mn(TDCPP)Cl] (1) and [Ru(TDCPP)CO] (2) as catalysts have been achieved. The "1 + H 2O 2" and "2 + 2,6-Cl 2pyNO" protocols afforded trans-epoxides selectively in good yields (up to 99%) with up to >99:1 trans-selectivity.
Persistent Identifierhttp://hdl.handle.net/10722/70309
ISSN
1523-7060
2023 Impact Factor: 4.9
2023 SCImago Journal Rankings: 1.245
ISI Accession Number ID
WOS:000221278500020
References
References in Scopus

 

DC FieldValueLanguage
dc.contributor.authorChan, WKen_HK
dc.contributor.authorLiu, Pen_HK
dc.contributor.authorYu, WYen_HK
dc.contributor.authorWong, MKen_HK
dc.contributor.authorChe, CMen_HK
dc.date.accessioned2010-09-06T06:21:40Z-
dc.date.available2010-09-06T06:21:40Z-
dc.date.issued2004en_HK
dc.identifier.citationOrganic Letters, 2004, v. 6 n. 10, p. 1597-1599en_HK
dc.identifier.issn1523-7060en_HK
dc.identifier.urihttp://hdl.handle.net/10722/70309-
dc.description.abstractHighly diastereoselective epoxidations of allyl-substituted cycloalkenes including allylic alcohols, esters, and amines using sterically bulky metalloporphyrins [Mn(TDCPP)Cl] (1) and [Ru(TDCPP)CO] (2) as catalysts have been achieved. The "1 + H 2O 2" and "2 + 2,6-Cl 2pyNO" protocols afforded trans-epoxides selectively in good yields (up to 99%) with up to >99:1 trans-selectivity.en_HK
dc.languageengen_HK
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/orlef7/index.htmlen_HK
dc.relation.ispartofOrganic Lettersen_HK
dc.titleHighly diastereoselective epoxidation of allyl-substituted cycloalkenes catalyzed by metalloporphyrinsen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1523-7060&volume=6&spage=1597&epage=1599&date=2004&atitle=Highly+diastereoselective+epoxidation+of+allyl-substituted+cycloalkenes+catalyzed+by+metalloporphyrinsen_HK
dc.identifier.emailChe, CM:cmche@hku.hken_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ol0496475en_HK
dc.identifier.scopuseid_2-s2.0-2542556021en_HK
dc.identifier.hkuros91402en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-2542556021&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume6en_HK
dc.identifier.issue10en_HK
dc.identifier.spage1597en_HK
dc.identifier.epage1599en_HK
dc.identifier.isiWOS:000221278500020-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridChan, WK=36545712200en_HK
dc.identifier.scopusauthoridLiu, P=36727836300en_HK
dc.identifier.scopusauthoridYu, WY=7403913673en_HK
dc.identifier.scopusauthoridWong, MK=7403908449en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK
dc.identifier.issnl1523-7052-

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