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Article: Ruthenium-catalyzed oxidative cleavage of olefins to aldehydes

TitleRuthenium-catalyzed oxidative cleavage of olefins to aldehydes
Authors
Yang, DZhang, C
Issue Date2001
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/joc
Citation
Journal Of Organic Chemistry, 2001, v. 66 n. 14, p. 4814-4818 How to Cite?
DOI: http://dx.doi.org/10.1021/jo010122p
AbstractThree oxidation protocols have been developed to cleave olefins to carbonyl compounds with ruthenium trichloride as catalyst (3.5 mol %). These methods convert olefins that are not fully substituted to aldehydes rather than carboxylic acids. While aryl olefins were cleaved to aromatic aldehydes in excellent yields by using the system of RuCl3-Oxone-NaHCO3 in CH3CN-H2O (1.5:1), aliphatic olefins were converted into alkyl aldehydes with RuCl3-NaIO4 in 1,2-dichloroethane-H2O (1:1) in good to excellent yields. It is noteworthy that terminal aliphatic olefins were cleaved to the corresponding aldehydes in excellent yields by using RuCl3-NaIO4 in CH3CN-H2O (6:1).
Persistent Identifierhttp://hdl.handle.net/10722/70400
ISSN
0022-3263
2023 Impact Factor: 3.3
2023 SCImago Journal Rankings: 0.724
ISI Accession Number ID
WOS:000169785500013
References
References in Scopus

 

DC FieldValueLanguage
dc.contributor.authorYang, Den_HK
dc.contributor.authorZhang, Cen_HK
dc.date.accessioned2010-09-06T06:22:31Z-
dc.date.available2010-09-06T06:22:31Z-
dc.date.issued2001en_HK
dc.identifier.citationJournal Of Organic Chemistry, 2001, v. 66 n. 14, p. 4814-4818en_HK
dc.identifier.issn0022-3263en_HK
dc.identifier.urihttp://hdl.handle.net/10722/70400-
dc.description.abstractThree oxidation protocols have been developed to cleave olefins to carbonyl compounds with ruthenium trichloride as catalyst (3.5 mol %). These methods convert olefins that are not fully substituted to aldehydes rather than carboxylic acids. While aryl olefins were cleaved to aromatic aldehydes in excellent yields by using the system of RuCl3-Oxone-NaHCO3 in CH3CN-H2O (1.5:1), aliphatic olefins were converted into alkyl aldehydes with RuCl3-NaIO4 in 1,2-dichloroethane-H2O (1:1) in good to excellent yields. It is noteworthy that terminal aliphatic olefins were cleaved to the corresponding aldehydes in excellent yields by using RuCl3-NaIO4 in CH3CN-H2O (6:1).en_HK
dc.languageengen_HK
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/jocen_HK
dc.relation.ispartofJournal of Organic Chemistryen_HK
dc.titleRuthenium-catalyzed oxidative cleavage of olefins to aldehydesen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0022-3263&volume=66&spage=4814&epage=4818&date=2001&atitle=Ruthenium-catalyzed+oxidative+cleavage+of+olefins+to+aldehydesen_HK
dc.identifier.emailYang, D:yangdan@hku.hken_HK
dc.identifier.authorityYang, D=rp00825en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/jo010122pen_HK
dc.identifier.pmid11442410-
dc.identifier.scopuseid_2-s2.0-0035854317en_HK
dc.identifier.hkuros68423en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0035854317&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume66en_HK
dc.identifier.issue14en_HK
dc.identifier.spage4814en_HK
dc.identifier.epage4818en_HK
dc.identifier.isiWOS:000169785500013-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridYang, D=7404800756en_HK
dc.identifier.scopusauthoridZhang, C=7405494641en_HK
dc.identifier.issnl0022-3263-

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