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Article: A modified suspension spray combined with particle gradation method for preparation of protonic ceramic membrane fuel cells

TitleA modified suspension spray combined with particle gradation method for preparation of protonic ceramic membrane fuel cells
Authors
KeywordsBazr0.1Ce0.7Y0.2O3-Δ
Interface
Particle Gradation
Solid Oxide Fuel Cells
Suspension Spray
Issue Date2008
PublisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jpowsour
Citation
Journal of Power Sources, 2008, v. 179 n. 2, p. 576-583 How to Cite?
AbstractIn order to prepare a dense proton-conductive Ba(Zr0.1Ce0.7)Y0.2O3-δ (BZCY7) electrolyte membrane, a proper anode composition with 65% Ni2O3 in weight ratio was determined after investigating the effects of anode compositions on anode shrinkages for co-sintering. The thermal expansion margins between sintered anodes and electrolytes, which were less than 1% below 750 °C, also showed good thermal expansion compatibility. A suspension spray combined with particle gradation method had been introduced to prepare dense electrolyte membrane on porous anode support. After a heat treatment at 1400 °C for 5 h, a cell with La0.5Sr0.5CoO3-δ (LSCO) cathode was assembled and tested with hydrogen and ammonia as fuels. The outputs reached as high as 330 mW cm-2 in hydrogen and 300 mW cm-2 in ammonia at 700 °C, respectively. Comparing with the interface of another cell prepared by dry-pressing method, this one also showed a good interface contact between electrodes and electrolyte. To sum up, this combined technique can be considered as commercial fabrication technology candidate. © 2008 Elsevier B.V. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/91016
ISSN
2023 Impact Factor: 8.1
2023 SCImago Journal Rankings: 1.857
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorXie, Ken_HK
dc.contributor.authorYan, Ren_HK
dc.contributor.authorDong, Den_HK
dc.contributor.authorWang, Sen_HK
dc.contributor.authorChen, Xen_HK
dc.contributor.authorJiang, Ten_HK
dc.contributor.authorLin, Ben_HK
dc.contributor.authorWei, Men_HK
dc.contributor.authorLiu, Xen_HK
dc.contributor.authorMeng, Gen_HK
dc.date.accessioned2010-09-17T10:11:47Z-
dc.date.available2010-09-17T10:11:47Z-
dc.date.issued2008en_HK
dc.identifier.citationJournal of Power Sources, 2008, v. 179 n. 2, p. 576-583en_HK
dc.identifier.issn0378-7753en_HK
dc.identifier.urihttp://hdl.handle.net/10722/91016-
dc.description.abstractIn order to prepare a dense proton-conductive Ba(Zr0.1Ce0.7)Y0.2O3-δ (BZCY7) electrolyte membrane, a proper anode composition with 65% Ni2O3 in weight ratio was determined after investigating the effects of anode compositions on anode shrinkages for co-sintering. The thermal expansion margins between sintered anodes and electrolytes, which were less than 1% below 750 °C, also showed good thermal expansion compatibility. A suspension spray combined with particle gradation method had been introduced to prepare dense electrolyte membrane on porous anode support. After a heat treatment at 1400 °C for 5 h, a cell with La0.5Sr0.5CoO3-δ (LSCO) cathode was assembled and tested with hydrogen and ammonia as fuels. The outputs reached as high as 330 mW cm-2 in hydrogen and 300 mW cm-2 in ammonia at 700 °C, respectively. Comparing with the interface of another cell prepared by dry-pressing method, this one also showed a good interface contact between electrodes and electrolyte. To sum up, this combined technique can be considered as commercial fabrication technology candidate. © 2008 Elsevier B.V. All rights reserved.en_HK
dc.languageengen_HK
dc.publisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jpowsouren_HK
dc.relation.ispartofJournal of Power Sourcesen_HK
dc.subjectBazr0.1Ce0.7Y0.2O3-Δen_HK
dc.subjectInterfaceen_HK
dc.subjectParticle Gradationen_HK
dc.subjectSolid Oxide Fuel Cellsen_HK
dc.subjectSuspension Sprayen_HK
dc.titleA modified suspension spray combined with particle gradation method for preparation of protonic ceramic membrane fuel cellsen_HK
dc.typeArticleen_HK
dc.identifier.emailLin, B:blin@hku.hken_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/j.jpowsour.2008.01.064en_HK
dc.identifier.scopuseid_2-s2.0-40849141922en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-40849141922&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume179en_HK
dc.identifier.issue2en_HK
dc.identifier.spage576en_HK
dc.identifier.epage583en_HK
dc.identifier.isiWOS:000255299900019-
dc.identifier.issnl0378-7753-

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