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Article: Efficient gold(I)-catalyzed direct intramolecular hydroalkylation of unactivated alkenes with α-ketones

TitleEfficient gold(I)-catalyzed direct intramolecular hydroalkylation of unactivated alkenes with α-ketones
Authors
Xiao, YPLiu, XYChe, CM
Keywordscyclic compounds
gold
homogeneous catalysis
hydroalkylation
unactivated alkenes
Issue Date2011
PublisherWiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home
Citation
Angewandte Chemie - International Edition, 2011, v. 50 n. 21, p. 4937-4941 How to Cite?
DOI: http://dx.doi.org/10.1002/anie.201100044
AbstractEasy access by gold: The Au I-catalyzed title reaction provides simple and efficient access to highly substituted cyclic compounds with excellent yields and good diastereoselectivity. This transformation constitutes the first example of transition-metal-catalyzed direct hydroalkylation of unactivated alkenes with simple α-ketone groups in the absence of additive reagents. Bn=benzyl, Ts=tosyl. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Persistent Identifierhttp://hdl.handle.net/10722/134352
ISSN
1433-7851
2021 Impact Factor: 16.823
2020 SCImago Journal Rankings: 5.831
ISI Accession Number ID
WOS:000290664400029
Funding AgencyGrant Number
University of Hong Kong
Hong Kong Research Grants Council
University Grants Committee of the Hong Kong SAR of ChinaAoE/P-10/01
Croucher Foundation of Hong Kong
CASGJHZ200816
Funding Information:

We are thankful for the financial support of The University of Hong Kong (University Development Fund), the Hong Kong Research Grants Council, and the University Grants Committee of the Hong Kong SAR of China (Area of Excellence Scheme, AoE/P-10/01). Y.-P.X. thanks the Croucher Foundation of Hong Kong and the External Cooperation Program of CAS (GJHZ200816).

References
References in Scopus
Grants
Institute of molecular technology for drug discovery and synthesis

 

DC FieldValueLanguage
dc.contributor.authorXiao, YPen_HK
dc.contributor.authorLiu, XYen_HK
dc.contributor.authorChe, CMen_HK
dc.date.accessioned2011-06-17T09:18:29Z-
dc.date.available2011-06-17T09:18:29Z-
dc.date.issued2011en_HK
dc.identifier.citationAngewandte Chemie - International Edition, 2011, v. 50 n. 21, p. 4937-4941en_HK
dc.identifier.issn1433-7851en_HK
dc.identifier.urihttp://hdl.handle.net/10722/134352-
dc.description.abstractEasy access by gold: The Au I-catalyzed title reaction provides simple and efficient access to highly substituted cyclic compounds with excellent yields and good diastereoselectivity. This transformation constitutes the first example of transition-metal-catalyzed direct hydroalkylation of unactivated alkenes with simple α-ketone groups in the absence of additive reagents. Bn=benzyl, Ts=tosyl. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en_HK
dc.languageengen_US
dc.publisherWiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/homeen_HK
dc.relation.ispartofAngewandte Chemie - International Editionen_HK
dc.subjectcyclic compoundsen_HK
dc.subjectgolden_HK
dc.subjecthomogeneous catalysisen_HK
dc.subjecthydroalkylationen_HK
dc.subjectunactivated alkenesen_HK
dc.titleEfficient gold(I)-catalyzed direct intramolecular hydroalkylation of unactivated alkenes with α-ketonesen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1433-7851&volume=50&issue=21&spage=4937&epage=4941&date=2011&atitle=Efficient+gold(I)-catalyzed+direct+intramolecular+hydroalkylation+of+unactivated+alkenes+with+α-ketones-
dc.identifier.emailChe, CM:cmche@hku.hken_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/anie.201100044en_HK
dc.identifier.pmid21538740-
dc.identifier.scopuseid_2-s2.0-79955760094en_HK
dc.identifier.hkuros185602en_US
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-79955760094&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume50en_HK
dc.identifier.issue21en_HK
dc.identifier.spage4937en_HK
dc.identifier.epage4941en_HK
dc.identifier.isiWOS:000290664400029-
dc.publisher.placeGermanyen_HK
dc.relation.projectInstitute of molecular technology for drug discovery and synthesis-
dc.identifier.scopusauthoridXiao, YP=7403260506en_HK
dc.identifier.scopusauthoridLiu, XY=48662515100en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK
dc.identifier.issnl1433-7851-

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