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- Publisher Website: 10.1016/S0277-5387(00)83049-1
- Scopus: eid_2-s2.0-0000919389
- WOS: WOS:A1993MD05400006
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Article: Synthesis and reactivity of dihydroxoruthenium(IV) complex of tetramesitylporphyrin. Aerobic epoxidation of norbornene by ruthenium porphyrins
Title | Synthesis and reactivity of dihydroxoruthenium(IV) complex of tetramesitylporphyrin. Aerobic epoxidation of norbornene by ruthenium porphyrins |
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Authors | |
Issue Date | 1993 |
Publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly |
Citation | Polyhedron, 1993, v. 12 n. 19, p. 2331-2334 How to Cite? |
Abstract | Treatment of Ru(TMP)(CO) with m-CPBA in CH2Cl2/EtOH afforded Ru (TMP)(OH)2, isolated as air-stable violet crystals. Ru(TMP)(OH)2 in paramagnetic (μeff ca 2.7 B.M.) and displays broad 1H NMR signals with paramagnetic isotropic shifts. The IR spectrum shows a band at 760 cm-1 assignable to the RuO stretch. Ru(TMP)(OH)2 is capable of catalysing aerobic epoxidation of alkenes under mild conditions. © 1993. |
Persistent Identifier | http://hdl.handle.net/10722/167309 |
ISSN | 2023 Impact Factor: 2.4 2023 SCImago Journal Rankings: 0.379 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Leung, WH | en_US |
dc.contributor.author | Che, CM | en_US |
dc.contributor.author | Yeung, CH | en_US |
dc.contributor.author | Poo, CK | en_US |
dc.date.accessioned | 2012-10-08T03:05:30Z | - |
dc.date.available | 2012-10-08T03:05:30Z | - |
dc.date.issued | 1993 | en_US |
dc.identifier.citation | Polyhedron, 1993, v. 12 n. 19, p. 2331-2334 | en_US |
dc.identifier.issn | 0277-5387 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/167309 | - |
dc.description.abstract | Treatment of Ru(TMP)(CO) with m-CPBA in CH2Cl2/EtOH afforded Ru (TMP)(OH)2, isolated as air-stable violet crystals. Ru(TMP)(OH)2 in paramagnetic (μeff ca 2.7 B.M.) and displays broad 1H NMR signals with paramagnetic isotropic shifts. The IR spectrum shows a band at 760 cm-1 assignable to the RuO stretch. Ru(TMP)(OH)2 is capable of catalysing aerobic epoxidation of alkenes under mild conditions. © 1993. | en_US |
dc.language | eng | en_US |
dc.publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly | en_US |
dc.relation.ispartof | Polyhedron | en_US |
dc.title | Synthesis and reactivity of dihydroxoruthenium(IV) complex of tetramesitylporphyrin. Aerobic epoxidation of norbornene by ruthenium porphyrins | en_US |
dc.type | Article | en_US |
dc.identifier.email | Che, CM:cmche@hku.hk | en_US |
dc.identifier.authority | Che, CM=rp00670 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1016/S0277-5387(00)83049-1 | - |
dc.identifier.scopus | eid_2-s2.0-0000919389 | en_US |
dc.identifier.volume | 12 | en_US |
dc.identifier.issue | 19 | en_US |
dc.identifier.spage | 2331 | en_US |
dc.identifier.epage | 2334 | en_US |
dc.identifier.isi | WOS:A1993MD05400006 | - |
dc.publisher.place | Netherlands | en_US |
dc.identifier.scopusauthorid | Leung, WH=7201504510 | en_US |
dc.identifier.scopusauthorid | Che, CM=7102442791 | en_US |
dc.identifier.scopusauthorid | Yeung, CH=7201354141 | en_US |
dc.identifier.scopusauthorid | Poo, CK=24303541000 | en_US |
dc.identifier.issnl | 0277-5387 | - |