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- Publisher Website: 10.1002/anie.200351178
- Scopus: eid_2-s2.0-0042530482
- PMID: 12888965
- WOS: WOS:000184548700011
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Article: First observation of alkali metal ion induced trans-cis isomerization of palladium(II) phosphane complexes containing crown ether moieties
Title | First observation of alkali metal ion induced trans-cis isomerization of palladium(II) phosphane complexes containing crown ether moieties |
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Authors | |
Keywords | Alkali metals Crown compounds Host-guest systems Isomerization Palladium |
Issue Date | 2003 |
Publisher | Wiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home |
Citation | Angewandte Chemie - International Edition, 2003, v. 42 n. 29, p. 3385-3388 How to Cite? |
Abstract | Ion switches: The addition of small metal ions (such as Li+ and Na+) to transpalladium(II) complexes of PPh2-substituted benzo[15]crown-5 and benzo[18]-crown-6 results in the formation of 1:1 trans adducts. However, the addition of large alkali ions (such as K+, Rb+, and Cs+) enforces the complexes to undergo a trans-cis isomerization to enable formation of intramolecular sandwich adducts (see schematic representation). |
Persistent Identifier | http://hdl.handle.net/10722/167824 |
ISSN | 2023 Impact Factor: 16.1 2023 SCImago Journal Rankings: 5.300 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Yam, VWW | en_US |
dc.contributor.author | Lu, XX | en_US |
dc.contributor.author | Ko, CC | en_US |
dc.date.accessioned | 2012-10-08T03:11:59Z | - |
dc.date.available | 2012-10-08T03:11:59Z | - |
dc.date.issued | 2003 | en_US |
dc.identifier.citation | Angewandte Chemie - International Edition, 2003, v. 42 n. 29, p. 3385-3388 | en_US |
dc.identifier.issn | 1433-7851 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/167824 | - |
dc.description.abstract | Ion switches: The addition of small metal ions (such as Li+ and Na+) to transpalladium(II) complexes of PPh2-substituted benzo[15]crown-5 and benzo[18]-crown-6 results in the formation of 1:1 trans adducts. However, the addition of large alkali ions (such as K+, Rb+, and Cs+) enforces the complexes to undergo a trans-cis isomerization to enable formation of intramolecular sandwich adducts (see schematic representation). | en_US |
dc.language | eng | en_US |
dc.publisher | Wiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home | en_US |
dc.relation.ispartof | Angewandte Chemie - International Edition | en_US |
dc.subject | Alkali metals | - |
dc.subject | Crown compounds | - |
dc.subject | Host-guest systems | - |
dc.subject | Isomerization | - |
dc.subject | Palladium | - |
dc.title | First observation of alkali metal ion induced trans-cis isomerization of palladium(II) phosphane complexes containing crown ether moieties | en_US |
dc.type | Article | en_US |
dc.identifier.email | Yam, VWW:wwyam@hku.hk | en_US |
dc.identifier.authority | Yam, VWW=rp00822 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1002/anie.200351178 | en_US |
dc.identifier.pmid | 12888965 | - |
dc.identifier.scopus | eid_2-s2.0-0042530482 | en_US |
dc.identifier.hkuros | 92790 | - |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-0042530482&selection=ref&src=s&origin=recordpage | en_US |
dc.identifier.volume | 42 | en_US |
dc.identifier.issue | 29 | en_US |
dc.identifier.spage | 3385 | en_US |
dc.identifier.epage | 3388 | en_US |
dc.identifier.isi | WOS:000184548700011 | - |
dc.publisher.place | Germany | en_US |
dc.identifier.scopusauthorid | Yam, VWW=18539304700 | en_US |
dc.identifier.scopusauthorid | Lu, XX=7404839171 | en_US |
dc.identifier.scopusauthorid | Ko, CC=7202596455 | en_US |
dc.identifier.issnl | 1433-7851 | - |