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- Publisher Website: 10.1021/jp055069d
- Scopus: eid_2-s2.0-33644557999
- PMID: 16419981
- WOS: WOS:000235046100003
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Article: Resonance Raman investigation of the short-time photodissociation dynamics of the charge-transfer absorption of the i2-Benzene Complex in Benzene Solution
Title | Resonance Raman investigation of the short-time photodissociation dynamics of the charge-transfer absorption of the i2-Benzene Complex in Benzene Solution |
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Authors | |
Issue Date | 2006 |
Publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/jpca |
Citation | Journal Of Physical Chemistry A, 2006, v. 110 n. 3, p. 851-860 How to Cite? |
Abstract | Resonance Raman spectra were obtained for the I2-benzene complex in benzene solvent with excitation wavelengths in resonance with the CT-band absorption. These spectra indicate that the Franck-Condon region photodissociation dynamics have multidimensional character with motion mainly along the nominal I-I stretch mode v 18, the nominal symmetric benzene ring stretch mode v 5, and the nominal symmetric CCH bending v 7. There is also a small contribution from the nominal out-of-plane CH oop wag v 15. A preliminary resonance Raman intensity analysis was done, and the results for the I 2-benzene complex were compared to results previously reported for the 1-hexene-I2 complex. We briefly discuss the differences and similarities in the CT-band absorption excitation of an I2-benzene complex relative to those of an I 2-alkene complex. © 2006 American Chemical Society. |
Persistent Identifier | http://hdl.handle.net/10722/168006 |
ISSN | 2023 Impact Factor: 2.7 2023 SCImago Journal Rankings: 0.604 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Weng, KF | en_US |
dc.contributor.author | Shi, Y | en_US |
dc.contributor.author | Zheng, X | en_US |
dc.contributor.author | Phillips, DL | en_US |
dc.date.accessioned | 2012-10-08T03:14:01Z | - |
dc.date.available | 2012-10-08T03:14:01Z | - |
dc.date.issued | 2006 | en_US |
dc.identifier.citation | Journal Of Physical Chemistry A, 2006, v. 110 n. 3, p. 851-860 | en_US |
dc.identifier.issn | 1089-5639 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/168006 | - |
dc.description.abstract | Resonance Raman spectra were obtained for the I2-benzene complex in benzene solvent with excitation wavelengths in resonance with the CT-band absorption. These spectra indicate that the Franck-Condon region photodissociation dynamics have multidimensional character with motion mainly along the nominal I-I stretch mode v 18, the nominal symmetric benzene ring stretch mode v 5, and the nominal symmetric CCH bending v 7. There is also a small contribution from the nominal out-of-plane CH oop wag v 15. A preliminary resonance Raman intensity analysis was done, and the results for the I 2-benzene complex were compared to results previously reported for the 1-hexene-I2 complex. We briefly discuss the differences and similarities in the CT-band absorption excitation of an I2-benzene complex relative to those of an I 2-alkene complex. © 2006 American Chemical Society. | en_US |
dc.language | eng | en_US |
dc.publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/jpca | en_US |
dc.relation.ispartof | Journal of Physical Chemistry A | en_US |
dc.title | Resonance Raman investigation of the short-time photodissociation dynamics of the charge-transfer absorption of the i2-Benzene Complex in Benzene Solution | en_US |
dc.type | Article | en_US |
dc.identifier.email | Phillips, DL:phillips@hku.hk | en_US |
dc.identifier.authority | Phillips, DL=rp00770 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1021/jp055069d | en_US |
dc.identifier.pmid | 16419981 | - |
dc.identifier.scopus | eid_2-s2.0-33644557999 | en_US |
dc.identifier.hkuros | 161144 | - |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-33644557999&selection=ref&src=s&origin=recordpage | en_US |
dc.identifier.volume | 110 | en_US |
dc.identifier.issue | 3 | en_US |
dc.identifier.spage | 851 | en_US |
dc.identifier.epage | 860 | en_US |
dc.identifier.isi | WOS:000235046100003 | - |
dc.publisher.place | United States | en_US |
dc.identifier.scopusauthorid | Weng, KF=12753940600 | en_US |
dc.identifier.scopusauthorid | Shi, Y=8719070600 | en_US |
dc.identifier.scopusauthorid | Zheng, X=7404090253 | en_US |
dc.identifier.scopusauthorid | Phillips, DL=7404519365 | en_US |
dc.identifier.issnl | 1089-5639 | - |