File Download
There are no files associated with this item.
Links for fulltext
(May Require Subscription)
- Publisher Website: 10.1039/DT9880002879
- Scopus: eid_2-s2.0-37049072617
- WOS: WOS:A1988Q990700030
- Find via
Supplementary
- Citations:
- Appears in Collections:
Article: Co-ordination chemistry of ruthenium with chelating amine ligands: Synthesis and X-ray structural study of the N6-co-ordinated ruthenium(II) complex of 1,4,8,11-tetrakis(2-pyridylmethyl)-1,4,8,11-tetra-aza-cyclotetradecane
Title | Co-ordination chemistry of ruthenium with chelating amine ligands: Synthesis and X-ray structural study of the N6-co-ordinated ruthenium(II) complex of 1,4,8,11-tetrakis(2-pyridylmethyl)-1,4,8,11-tetra-aza-cyclotetradecane |
---|---|
Authors | |
Issue Date | 1988 |
Publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton |
Citation | Journal Of The Chemical Society, Dalton Transactions, 1988 n. 11, p. 2879-2883 How to Cite? |
Abstract | Reaction of K2[RuCl5(H2O)] with 1,4,8,11-tetrakis(2-pyridylmethyl)-1,4,8,11-tetra-azacyclotetradecane (L1) in ethanol yielded [RuII(HL1)][ClO4]3·H 2O (1). The E1/2 value for the RuIII/II couple is 1.17 V vs. a normal hydrogen electrode and the optical spectrum shows an intense dπ(Ru) → π*(pyridine) charge-transfer transition at 376 nm. The complex cation in (1) [space group P1, a = 10.674(2), b = 14.211(3), c = 14.507(4) Å, α = 92.77(3), β = 107.28(3), γ = 105.65(2)°, U = 2 003.5(7) Å3, Z = 2; R = 0.043 for 7 037 observed Mo-Kα data] is distorted octahedral with average Ru-N(tertiary amine) and Ru-N(pyridyl) bond distances of 2.191(3) and 2.075(3) Å respectively. |
Persistent Identifier | http://hdl.handle.net/10722/168188 |
ISSN | |
ISI Accession Number ID |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Che, CM | en_US |
dc.contributor.author | Tang, W | en_US |
dc.contributor.author | Mak, TCW | en_US |
dc.date.accessioned | 2012-10-08T03:16:06Z | - |
dc.date.available | 2012-10-08T03:16:06Z | - |
dc.date.issued | 1988 | en_US |
dc.identifier.citation | Journal Of The Chemical Society, Dalton Transactions, 1988 n. 11, p. 2879-2883 | en_US |
dc.identifier.issn | 1472-7773 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/168188 | - |
dc.description.abstract | Reaction of K2[RuCl5(H2O)] with 1,4,8,11-tetrakis(2-pyridylmethyl)-1,4,8,11-tetra-azacyclotetradecane (L1) in ethanol yielded [RuII(HL1)][ClO4]3·H 2O (1). The E1/2 value for the RuIII/II couple is 1.17 V vs. a normal hydrogen electrode and the optical spectrum shows an intense dπ(Ru) → π*(pyridine) charge-transfer transition at 376 nm. The complex cation in (1) [space group P1, a = 10.674(2), b = 14.211(3), c = 14.507(4) Å, α = 92.77(3), β = 107.28(3), γ = 105.65(2)°, U = 2 003.5(7) Å3, Z = 2; R = 0.043 for 7 037 observed Mo-Kα data] is distorted octahedral with average Ru-N(tertiary amine) and Ru-N(pyridyl) bond distances of 2.191(3) and 2.075(3) Å respectively. | en_US |
dc.language | eng | en_US |
dc.publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton | en_US |
dc.relation.ispartof | Journal of the Chemical Society, Dalton Transactions | en_US |
dc.title | Co-ordination chemistry of ruthenium with chelating amine ligands: Synthesis and X-ray structural study of the N6-co-ordinated ruthenium(II) complex of 1,4,8,11-tetrakis(2-pyridylmethyl)-1,4,8,11-tetra-aza-cyclotetradecane | en_US |
dc.type | Article | en_US |
dc.identifier.email | Che, CM:cmche@hku.hk | en_US |
dc.identifier.authority | Che, CM=rp00670 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1039/DT9880002879 | en_US |
dc.identifier.scopus | eid_2-s2.0-37049072617 | en_US |
dc.identifier.issue | 11 | en_US |
dc.identifier.spage | 2879 | en_US |
dc.identifier.epage | 2883 | en_US |
dc.identifier.isi | WOS:A1988Q990700030 | - |
dc.publisher.place | United Kingdom | en_US |
dc.identifier.scopusauthorid | Che, CM=7102442791 | en_US |
dc.identifier.scopusauthorid | Tang, W=15121154000 | en_US |
dc.identifier.scopusauthorid | Mak, TCW=7401931058 | en_US |
dc.identifier.issnl | 1364-5447 | - |