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Article: Ligand C-C bond cleavage on ruthenium: Observation of a reversible ruthenium(V)-imido/ruthenium(II)-amine couple and X-ray crystal structure of [ru(bpy)2(NH=CMe2)2](PF6) 2 (bpy = 2,2′-bipyridine)

TitleLigand C-C bond cleavage on ruthenium: Observation of a reversible ruthenium(V)-imido/ruthenium(II)-amine couple and X-ray crystal structure of [ru(bpy)2(NH=CMe2)2](PF6) 2 (bpy = 2,2′-bipyridine)
Authors
Wong, KYChe, CMLi, CKChiu, WHZhou, ZYMak, TCW
Issue Date1992
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp
Citation
Journal Of The Chemical Society, Chemical Communications, 1992 n. 10, p. 754-756 How to Cite?
DOI: http://dx.doi.org/10.1039/C39920000754
AbstractA reversible three-proton three-electron couple has been observed for the electrochemical oxidation of cis-[Ru(bpy)2(L)]2+ (L = 2,3-dimethyl-2,3-diaminobutane) in aqueous acidic solution; controlled-potential electrochemical oxidation of cis-[Ru(bpy)2(L)]2+ led to C-C bond cleavage in L and formation of cis-[Ru(bpy)2(NH=CMe 2)2]2+ whose structure has been determined by X-ray crystallography.
Persistent Identifierhttp://hdl.handle.net/10722/168212
ISSN
0022-4936
ISI Accession Number ID
WOS:A1992HV41400014

 

DC FieldValueLanguage
dc.contributor.authorWong, KYen_US
dc.contributor.authorChe, CMen_US
dc.contributor.authorLi, CKen_US
dc.contributor.authorChiu, WHen_US
dc.contributor.authorZhou, ZYen_US
dc.contributor.authorMak, TCWen_US
dc.date.accessioned2012-10-08T03:16:19Z-
dc.date.available2012-10-08T03:16:19Z-
dc.date.issued1992en_US
dc.identifier.citationJournal Of The Chemical Society, Chemical Communications, 1992 n. 10, p. 754-756en_US
dc.identifier.issn0022-4936en_US
dc.identifier.urihttp://hdl.handle.net/10722/168212-
dc.description.abstractA reversible three-proton three-electron couple has been observed for the electrochemical oxidation of cis-[Ru(bpy)2(L)]2+ (L = 2,3-dimethyl-2,3-diaminobutane) in aqueous acidic solution; controlled-potential electrochemical oxidation of cis-[Ru(bpy)2(L)]2+ led to C-C bond cleavage in L and formation of cis-[Ru(bpy)2(NH=CMe 2)2]2+ whose structure has been determined by X-ray crystallography.en_US
dc.languageengen_US
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.aspen_US
dc.relation.ispartofJournal of the Chemical Society, Chemical Communicationsen_US
dc.titleLigand C-C bond cleavage on ruthenium: Observation of a reversible ruthenium(V)-imido/ruthenium(II)-amine couple and X-ray crystal structure of [ru(bpy)2(NH=CMe2)2](PF6) 2 (bpy = 2,2′-bipyridine)en_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/C39920000754en_US
dc.identifier.scopuseid_2-s2.0-37049077134en_US
dc.identifier.issue10en_US
dc.identifier.spage754en_US
dc.identifier.epage756en_US
dc.identifier.isiWOS:A1992HV41400014-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridWong, KY=7404760030en_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridLi, CK=8714186500en_US
dc.identifier.scopusauthoridChiu, WH=7201503487en_US
dc.identifier.scopusauthoridZhou, ZY=7406096262en_US
dc.identifier.scopusauthoridMak, TCW=7401931058en_US
dc.identifier.issnl0022-4936-

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