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- Publisher Website: 10.1039/C39900000820
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Article: Novel five-co-ordinate osmium-oxo complex stabilized by diaminato ligands. Synthesis, reactivities, and x-ray crystal structure of [OsO{NHC(Me) 2C(Me)2NH}{NH2C(Me)2C(Me) 2NH}]ClO4
Title | Novel five-co-ordinate osmium-oxo complex stabilized by diaminato ligands. Synthesis, reactivities, and x-ray crystal structure of [OsO{NHC(Me) 2C(Me)2NH}{NH2C(Me)2C(Me) 2NH}]ClO4 |
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Authors | |
Issue Date | 1990 |
Publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp |
Citation | Journal Of The Chemical Society, Chemical Communications, 1990 n. 11, p. 820-821 How to Cite? |
Abstract | The six-co-ordinate trans-[Os(L)2(O)2]2+ [L = NH2C(Me)2C(Me)2NH2] and five-co-ordinate [OsO{NHC(Me)2C(Me)2NH}{NH 2C(Me)2C(Me)2NH}]+ complexes are in equilibrium in solution; the X-ray structure of the five-co-ordinate square pyramidal OsVI-oxo complex has been determined with a measured Os=O distance of 1.72(2) Å. |
Persistent Identifier | http://hdl.handle.net/10722/168250 |
ISSN | |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Che, CM | en_US |
dc.contributor.author | Lam, MHW | en_US |
dc.contributor.author | Wang, RJ | en_US |
dc.contributor.author | Mak, TCW | en_US |
dc.date.accessioned | 2012-10-08T03:16:41Z | - |
dc.date.available | 2012-10-08T03:16:41Z | - |
dc.date.issued | 1990 | en_US |
dc.identifier.citation | Journal Of The Chemical Society, Chemical Communications, 1990 n. 11, p. 820-821 | en_US |
dc.identifier.issn | 0022-4936 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/168250 | - |
dc.description.abstract | The six-co-ordinate trans-[Os(L)2(O)2]2+ [L = NH2C(Me)2C(Me)2NH2] and five-co-ordinate [OsO{NHC(Me)2C(Me)2NH}{NH 2C(Me)2C(Me)2NH}]+ complexes are in equilibrium in solution; the X-ray structure of the five-co-ordinate square pyramidal OsVI-oxo complex has been determined with a measured Os=O distance of 1.72(2) Å. | en_US |
dc.language | eng | en_US |
dc.publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp | en_US |
dc.relation.ispartof | Journal of the Chemical Society, Chemical Communications | en_US |
dc.title | Novel five-co-ordinate osmium-oxo complex stabilized by diaminato ligands. Synthesis, reactivities, and x-ray crystal structure of [OsO{NHC(Me) 2C(Me)2NH}{NH2C(Me)2C(Me) 2NH}]ClO4 | en_US |
dc.type | Article | en_US |
dc.identifier.email | Che, CM:cmche@hku.hk | en_US |
dc.identifier.authority | Che, CM=rp00670 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1039/C39900000820 | en_US |
dc.identifier.scopus | eid_2-s2.0-37049089555 | en_US |
dc.identifier.issue | 11 | en_US |
dc.identifier.spage | 820 | en_US |
dc.identifier.epage | 821 | en_US |
dc.identifier.isi | WOS:A1990DK06400018 | - |
dc.publisher.place | United Kingdom | en_US |
dc.identifier.scopusauthorid | Che, CM=7102442791 | en_US |
dc.identifier.scopusauthorid | Lam, MHW=7202630175 | en_US |
dc.identifier.scopusauthorid | Wang, RJ=7405340385 | en_US |
dc.identifier.scopusauthorid | Mak, TCW=7401931058 | en_US |
dc.identifier.issnl | 0022-4936 | - |