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Article: Structural and mechanistic studies of co-ordination compounds. Part 30. Synthesis and characterization of some octahedral halogenoamine complexes of osmium(III)
Title | Structural and mechanistic studies of co-ordination compounds. Part 30. Synthesis and characterization of some octahedral halogenoamine complexes of osmium(III) |
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Authors | |
Issue Date | 1981 |
Publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton |
Citation | Journal Of The Chemical Society, Dalton Transactions, 1981 n. 8, p. 1697-1700 How to Cite? |
Abstract | A series of osmium(III) amine complexes of the types trans-[OsLCl2]+ [L = L1, bis(ethane-1,2-diamine); L2, 3,7-diazanonane-1,9-diamine; L3, 4,7-diazadecane-1,10-diamine; L4, 1,4,8,11-tetra-azacyclotetradecane; or L5, 1,4,8,12-tetra-azacyclopentadecane], trans-[OsLBr2]+ (L = L3, L4, or L5), and trans-[OsL3I2]+ has been prepared and characterized. All these complexes are low-spin monomeric species. The general synthetic methods and the electronic and i.r. absorption spectra of these complexes are discussed. |
Persistent Identifier | http://hdl.handle.net/10722/168263 |
ISSN | |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Poon, CK | en_US |
dc.contributor.author | Che, CM | en_US |
dc.contributor.author | Tang, TW | en_US |
dc.date.accessioned | 2012-10-08T03:16:47Z | - |
dc.date.available | 2012-10-08T03:16:47Z | - |
dc.date.issued | 1981 | en_US |
dc.identifier.citation | Journal Of The Chemical Society, Dalton Transactions, 1981 n. 8, p. 1697-1700 | en_US |
dc.identifier.issn | 1472-7773 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/168263 | - |
dc.description.abstract | A series of osmium(III) amine complexes of the types trans-[OsLCl2]+ [L = L1, bis(ethane-1,2-diamine); L2, 3,7-diazanonane-1,9-diamine; L3, 4,7-diazadecane-1,10-diamine; L4, 1,4,8,11-tetra-azacyclotetradecane; or L5, 1,4,8,12-tetra-azacyclopentadecane], trans-[OsLBr2]+ (L = L3, L4, or L5), and trans-[OsL3I2]+ has been prepared and characterized. All these complexes are low-spin monomeric species. The general synthetic methods and the electronic and i.r. absorption spectra of these complexes are discussed. | en_US |
dc.language | eng | en_US |
dc.publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton | en_US |
dc.relation.ispartof | Journal of the Chemical Society, Dalton Transactions | en_US |
dc.title | Structural and mechanistic studies of co-ordination compounds. Part 30. Synthesis and characterization of some octahedral halogenoamine complexes of osmium(III) | en_US |
dc.type | Article | en_US |
dc.identifier.email | Che, CM:cmche@hku.hk | en_US |
dc.identifier.authority | Che, CM=rp00670 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1039/DT9810001697 | en_US |
dc.identifier.scopus | eid_2-s2.0-37049106107 | en_US |
dc.identifier.issue | 8 | en_US |
dc.identifier.spage | 1697 | en_US |
dc.identifier.epage | 1700 | en_US |
dc.identifier.isi | WOS:A1981MC94100006 | - |
dc.publisher.place | United Kingdom | en_US |
dc.identifier.scopusauthorid | Poon, CK=7202673504 | en_US |
dc.identifier.scopusauthorid | Che, CM=7102442791 | en_US |
dc.identifier.scopusauthorid | Tang, TW=15222800500 | en_US |
dc.identifier.issnl | 1364-5447 | - |