File Download
There are no files associated with this item.
Links for fulltext
(May Require Subscription)
- Publisher Website: 10.1021/ja8047078
- Scopus: eid_2-s2.0-53549108902
- PMID: 18783224
- WOS: WOS:000259675500018
- Find via
Supplementary
- Citations:
- Appears in Collections:
Article: On the two-component microwave-mediated reaction of isonitriles with carboxylic acids: Regarding alleged formimidate carboxylate mixed anhydrides
Title | On the two-component microwave-mediated reaction of isonitriles with carboxylic acids: Regarding alleged formimidate carboxylate mixed anhydrides |
---|---|
Authors | |
Issue Date | 2008 |
Publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/jacsat/index.html |
Citation | Journal Of The American Chemical Society, 2008, v. 130 n. 40, p. 13222-13224 How to Cite? |
Abstract | Microwave induced two-component coupling (2CC) reaction of carboxylic acids with isonitriles gives rise to various N-formylamides. The formimidate carboxylate mixed anhydride (FCMA) is proposed as the reactive intermediate, which undergoes 1,3-O→N acyl transfer to give the observed product. The formation and survival of the labile FCMA system has been evaluated. Copyright © 2008 American Chemical Society. |
Persistent Identifier | http://hdl.handle.net/10722/168328 |
ISSN | 2023 Impact Factor: 14.4 2023 SCImago Journal Rankings: 5.489 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Li, X | en_US |
dc.contributor.author | Yuan, Y | en_US |
dc.contributor.author | Berkowitz, WF | en_US |
dc.contributor.author | Todaro, LJ | en_US |
dc.contributor.author | Danishefsky, SJ | en_US |
dc.date.accessioned | 2012-10-08T03:17:39Z | - |
dc.date.available | 2012-10-08T03:17:39Z | - |
dc.date.issued | 2008 | en_US |
dc.identifier.citation | Journal Of The American Chemical Society, 2008, v. 130 n. 40, p. 13222-13224 | en_US |
dc.identifier.issn | 0002-7863 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/168328 | - |
dc.description.abstract | Microwave induced two-component coupling (2CC) reaction of carboxylic acids with isonitriles gives rise to various N-formylamides. The formimidate carboxylate mixed anhydride (FCMA) is proposed as the reactive intermediate, which undergoes 1,3-O→N acyl transfer to give the observed product. The formation and survival of the labile FCMA system has been evaluated. Copyright © 2008 American Chemical Society. | en_US |
dc.language | eng | en_US |
dc.publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/jacsat/index.html | en_US |
dc.relation.ispartof | Journal of the American Chemical Society | en_US |
dc.subject.mesh | Amides - Chemistry | en_US |
dc.subject.mesh | Anhydrides - Chemistry | en_US |
dc.subject.mesh | Carboxylic Acids - Chemistry | en_US |
dc.subject.mesh | Formic Acids - Chemistry | en_US |
dc.subject.mesh | Microwaves | en_US |
dc.subject.mesh | Models, Molecular | en_US |
dc.subject.mesh | Molecular Structure | en_US |
dc.subject.mesh | Nitriles - Chemistry | en_US |
dc.title | On the two-component microwave-mediated reaction of isonitriles with carboxylic acids: Regarding alleged formimidate carboxylate mixed anhydrides | en_US |
dc.type | Article | en_US |
dc.identifier.email | Li, X:xuechenl@hku.hk | en_US |
dc.identifier.authority | Li, X=rp00742 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1021/ja8047078 | en_US |
dc.identifier.pmid | 18783224 | - |
dc.identifier.scopus | eid_2-s2.0-53549108902 | en_US |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-53549108902&selection=ref&src=s&origin=recordpage | en_US |
dc.identifier.volume | 130 | en_US |
dc.identifier.issue | 40 | en_US |
dc.identifier.spage | 13222 | en_US |
dc.identifier.epage | 13224 | en_US |
dc.identifier.eissn | 1520-5126 | - |
dc.identifier.isi | WOS:000259675500018 | - |
dc.publisher.place | United States | en_US |
dc.identifier.scopusauthorid | Li, X=24168958800 | en_US |
dc.identifier.scopusauthorid | Yuan, Y=35180688100 | en_US |
dc.identifier.scopusauthorid | Berkowitz, WF=55275603600 | en_US |
dc.identifier.scopusauthorid | Todaro, LJ=7004233791 | en_US |
dc.identifier.scopusauthorid | Danishefsky, SJ=7202925243 | en_US |
dc.identifier.issnl | 0002-7863 | - |