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- Publisher Website: 10.1007/BF00401306
- Scopus: eid_2-s2.0-0025840465
- PMID: 24233934
- WOS: WOS:A1991GW30800016
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Article: Entrapping of organic wastes by coordination clathrates
Title | Entrapping of organic wastes by coordination clathrates |
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Authors | |
Issue Date | 1991 |
Citation | Environmental Monitoring and Assessment, 1991, v. 19, n. 1-3, p. 145-150 How to Cite? |
Abstract | The feasibility of the Hofmann clathrates Ni(CN)2(NH3)·G(G=guest molecule) and the octahedral Werner-type complexes Ni(X)2(L)4 (X=NCS, NCO, CH3CO2, C6H5CO2; L=Py, 4-Mepy) as a scavenger for organic substrates in a polluted aqueous or organic medium is dependent on the complex lability, thermal stability and reversibility in solvent trapping which can be conveniently studied by thermogravimetric means. Besides the parent monomeric octahedral complexes, all the thermal decompositional intermediates, namely, monomeric tetrahedral, dimeric octahedral and polymeric octahedral, are also potential scavengers for selected organic substances though they operate via a cycle of bond-making and bond-breaking processes. © 1991 Kluwer Academic Publishers. |
Persistent Identifier | http://hdl.handle.net/10722/219401 |
ISSN | 2023 Impact Factor: 2.9 2023 SCImago Journal Rankings: 0.643 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Hor, T. S Andy | - |
dc.contributor.author | Leong, Ying Phooi | - |
dc.contributor.author | Phang, Lai Tee | - |
dc.date.accessioned | 2015-09-23T02:56:58Z | - |
dc.date.available | 2015-09-23T02:56:58Z | - |
dc.date.issued | 1991 | - |
dc.identifier.citation | Environmental Monitoring and Assessment, 1991, v. 19, n. 1-3, p. 145-150 | - |
dc.identifier.issn | 0167-6369 | - |
dc.identifier.uri | http://hdl.handle.net/10722/219401 | - |
dc.description.abstract | The feasibility of the Hofmann clathrates Ni(CN)2(NH3)·G(G=guest molecule) and the octahedral Werner-type complexes Ni(X)2(L)4 (X=NCS, NCO, CH3CO2, C6H5CO2; L=Py, 4-Mepy) as a scavenger for organic substrates in a polluted aqueous or organic medium is dependent on the complex lability, thermal stability and reversibility in solvent trapping which can be conveniently studied by thermogravimetric means. Besides the parent monomeric octahedral complexes, all the thermal decompositional intermediates, namely, monomeric tetrahedral, dimeric octahedral and polymeric octahedral, are also potential scavengers for selected organic substances though they operate via a cycle of bond-making and bond-breaking processes. © 1991 Kluwer Academic Publishers. | - |
dc.language | eng | - |
dc.relation.ispartof | Environmental Monitoring and Assessment | - |
dc.title | Entrapping of organic wastes by coordination clathrates | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1007/BF00401306 | - |
dc.identifier.pmid | 24233934 | - |
dc.identifier.scopus | eid_2-s2.0-0025840465 | - |
dc.identifier.volume | 19 | - |
dc.identifier.issue | 1-3 | - |
dc.identifier.spage | 145 | - |
dc.identifier.epage | 150 | - |
dc.identifier.eissn | 1573-2959 | - |
dc.identifier.isi | WOS:A1991GW30800016 | - |
dc.identifier.issnl | 0167-6369 | - |