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- Publisher Website: 10.1039/c3cc45500a
- Scopus: eid_2-s2.0-84884299563
- PMID: 23999555
- WOS: WOS:000324546000011
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Article: Silver-catalysed intramolecular hydroamination of alkynes with trichloroacetimidates
| Title | Silver-catalysed intramolecular hydroamination of alkynes with trichloroacetimidates |
|---|---|
| Authors | |
| Issue Date | 2013 |
| Citation | Chemical Communications, 2013, v. 49, n. 81, p. 9272-9274 How to Cite? |
| Abstract | Silver(i) complexes catalyse the intramolecular addition of trichloroacetimidates to alkynes. In the absence of a ligand, the selectivity of the reaction is dependent upon the nature of the counter-anion and solvent. The introduction of non-chelating nitrogeneous ligands suppresses competitive Brønsted acid catalysis, improving the yield and selectivity of the reaction. © 2013 The Royal Society of Chemistry. |
| Persistent Identifier | http://hdl.handle.net/10722/219716 |
| ISSN | 2021 Impact Factor: 6.065 2020 SCImago Journal Rankings: 1.837 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Wong, Valerie H L | - |
| dc.contributor.author | Hor, T. S Andy | - |
| dc.contributor.author | Hii, King Kuok | - |
| dc.date.accessioned | 2015-09-23T02:57:47Z | - |
| dc.date.available | 2015-09-23T02:57:47Z | - |
| dc.date.issued | 2013 | - |
| dc.identifier.citation | Chemical Communications, 2013, v. 49, n. 81, p. 9272-9274 | - |
| dc.identifier.issn | 1359-7345 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/219716 | - |
| dc.description.abstract | Silver(i) complexes catalyse the intramolecular addition of trichloroacetimidates to alkynes. In the absence of a ligand, the selectivity of the reaction is dependent upon the nature of the counter-anion and solvent. The introduction of non-chelating nitrogeneous ligands suppresses competitive Brønsted acid catalysis, improving the yield and selectivity of the reaction. © 2013 The Royal Society of Chemistry. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Chemical Communications | - |
| dc.title | Silver-catalysed intramolecular hydroamination of alkynes with trichloroacetimidates | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1039/c3cc45500a | - |
| dc.identifier.pmid | 23999555 | - |
| dc.identifier.scopus | eid_2-s2.0-84884299563 | - |
| dc.identifier.volume | 49 | - |
| dc.identifier.issue | 81 | - |
| dc.identifier.spage | 9272 | - |
| dc.identifier.epage | 9274 | - |
| dc.identifier.eissn | 1364-548X | - |
| dc.identifier.isi | WOS:000324546000011 | - |
| dc.identifier.issnl | 1359-7345 | - |