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- Publisher Website: 10.1021/ol403406y
- Scopus: eid_2-s2.0-84896749154
- PMID: 24372349
- WOS: WOS:000330098400051
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Article: Copper-catalyzed trifluoromethylselenolation of aryl and alkyl halides: The silver effect in transmetalation
Title | Copper-catalyzed trifluoromethylselenolation of aryl and alkyl halides: The silver effect in transmetalation |
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Authors | |
Issue Date | 2014 |
Citation | Organic Letters, 2014, v. 16, n. 2, p. 524-527 How to Cite? |
Abstract | A catalytic trifluoromethylselenolation of aryl and alkyl halides by a Cu(I) catalyst has been developed. A key intermediate, [(phen)Cu(SeCF3)]2 (5) was successfully isolated and characterized by X-ray diffraction. The important role of silver in the transmetalation process during the catalytic cycle was elucidated. A wide range of trifluoromethylselanes have been prepared from readily available starting materials from a method that tolerates various important functional groups. © 2013 American Chemical Society. |
Persistent Identifier | http://hdl.handle.net/10722/219744 |
ISSN | 2023 Impact Factor: 4.9 2023 SCImago Journal Rankings: 1.245 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Chen, Chaohuang | - |
dc.contributor.author | Hou, Chuanqi | - |
dc.contributor.author | Wang, Yuguang | - |
dc.contributor.author | Hor, T. S Andy | - |
dc.contributor.author | Weng, Zhiqiang | - |
dc.date.accessioned | 2015-09-23T02:57:52Z | - |
dc.date.available | 2015-09-23T02:57:52Z | - |
dc.date.issued | 2014 | - |
dc.identifier.citation | Organic Letters, 2014, v. 16, n. 2, p. 524-527 | - |
dc.identifier.issn | 1523-7060 | - |
dc.identifier.uri | http://hdl.handle.net/10722/219744 | - |
dc.description.abstract | A catalytic trifluoromethylselenolation of aryl and alkyl halides by a Cu(I) catalyst has been developed. A key intermediate, [(phen)Cu(SeCF3)]2 (5) was successfully isolated and characterized by X-ray diffraction. The important role of silver in the transmetalation process during the catalytic cycle was elucidated. A wide range of trifluoromethylselanes have been prepared from readily available starting materials from a method that tolerates various important functional groups. © 2013 American Chemical Society. | - |
dc.language | eng | - |
dc.relation.ispartof | Organic Letters | - |
dc.title | Copper-catalyzed trifluoromethylselenolation of aryl and alkyl halides: The silver effect in transmetalation | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1021/ol403406y | - |
dc.identifier.pmid | 24372349 | - |
dc.identifier.scopus | eid_2-s2.0-84896749154 | - |
dc.identifier.volume | 16 | - |
dc.identifier.issue | 2 | - |
dc.identifier.spage | 524 | - |
dc.identifier.epage | 527 | - |
dc.identifier.eissn | 1523-7052 | - |
dc.identifier.isi | WOS:000330098400051 | - |
dc.identifier.issnl | 1523-7052 | - |