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Article: Aryl-BIAN-ligated silver(i) trifluoromethoxide complex

TitleAryl-BIAN-ligated silver(i) trifluoromethoxide complex
Authors
Issue Date2015
Citation
Dalton Transactions, 2015, v. 44, n. 45, p. 19682-19686 How to Cite?
Abstract© The Royal Society of Chemistry.A reaction of acetonitrile-solvated AgOCF3 with 1 equiv. of Aryl-BIAN ligand in THF at room-temperature afforded the silver(i) complex (Aryl-BIAN)AgOCF3 (1) in 75% yield. The crystal structure of this silver(i) trifluoromethoxide was determined by single-crystal X-ray crystallography. The molecular structure of 1 shows the metal centre bound to one molecule of BIAN, one trifluoromethoxide and one THF solvate, resulting in a distorted tetrahedral silver. Density functional theory (DFT) calculations and the natural bond orbital (NBO) analysis were conducted to give insights into the electronic structure of 1 and the bonding characters of the OCF3 group. The reactivity of 1 towards trifluoromethoxylation of organic halides was also examined; a reaction with benzyl bromides gave the desired products of benzyl trifluoromethyl ethers in good to excellent yields.
Persistent Identifierhttp://hdl.handle.net/10722/237517
ISSN
2017 Impact Factor: 4.099
2015 SCImago Journal Rankings: 1.404
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorChen, Shouxiong-
dc.contributor.authorHuang, Yangjie-
dc.contributor.authorFang, Xin-
dc.contributor.authorLi, Haohong-
dc.contributor.authorZhang, Zhongxing-
dc.contributor.authorHor, T. S Andy-
dc.contributor.authorWeng, Zhiqiang-
dc.date.accessioned2017-01-16T06:09:23Z-
dc.date.available2017-01-16T06:09:23Z-
dc.date.issued2015-
dc.identifier.citationDalton Transactions, 2015, v. 44, n. 45, p. 19682-19686-
dc.identifier.issn1477-9226-
dc.identifier.urihttp://hdl.handle.net/10722/237517-
dc.description.abstract© The Royal Society of Chemistry.A reaction of acetonitrile-solvated AgOCF3 with 1 equiv. of Aryl-BIAN ligand in THF at room-temperature afforded the silver(i) complex (Aryl-BIAN)AgOCF3 (1) in 75% yield. The crystal structure of this silver(i) trifluoromethoxide was determined by single-crystal X-ray crystallography. The molecular structure of 1 shows the metal centre bound to one molecule of BIAN, one trifluoromethoxide and one THF solvate, resulting in a distorted tetrahedral silver. Density functional theory (DFT) calculations and the natural bond orbital (NBO) analysis were conducted to give insights into the electronic structure of 1 and the bonding characters of the OCF3 group. The reactivity of 1 towards trifluoromethoxylation of organic halides was also examined; a reaction with benzyl bromides gave the desired products of benzyl trifluoromethyl ethers in good to excellent yields.-
dc.languageeng-
dc.relation.ispartofDalton Transactions-
dc.titleAryl-BIAN-ligated silver(i) trifluoromethoxide complex-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1039/c5dt02078f-
dc.identifier.scopuseid_2-s2.0-84947594502-
dc.identifier.hkuros285706-
dc.identifier.volume44-
dc.identifier.issue45-
dc.identifier.spage19682-
dc.identifier.epage19686-
dc.identifier.eissn1477-9234-
dc.identifier.isiWOS:000364912100033-

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