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Article: A strange nickel(I)-nickel(0) binuclear complex and its unexpected ethylene oligomerization

TitleA strange nickel(I)-nickel(0) binuclear complex and its unexpected ethylene oligomerization
Authors
Issue Date2007
Citation
Organometallics, 2007, v. 26, n. 12, p. 2950-2952 How to Cite?
AbstractThe unusual heterovalent bimetallic Ni1-Ni0 complex {[η-C5H4CH=N(C6F5)]Fe[η- C5H4PPh2]}2Ni2(Cl) (2) was isolated from the reaction between [η-C5H4CH= N(C6F5)]Fe[η-C5H4PPh 2] (1) and Ni(COD)2 in the presence of AlEtCl2 or AlCl3. Complex 2 has been crystallographically characterized and theoretically analyzed; it is catalytically active (TOF 90 500) and selective (91%) toward the formation of C4 oligomers from ethylene (300 psi) at 30 °C, the only other significant isomer formed being C6. © 2007 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/237575
ISSN
2017 Impact Factor: 4.051
2015 SCImago Journal Rankings: 2.043
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorWeng, Zhiqiang-
dc.contributor.authorTeo, Shihui-
dc.contributor.authorLiu, Zhi Pan-
dc.contributor.authorAndy Hor, T. S.-
dc.date.accessioned2017-01-16T06:09:54Z-
dc.date.available2017-01-16T06:09:54Z-
dc.date.issued2007-
dc.identifier.citationOrganometallics, 2007, v. 26, n. 12, p. 2950-2952-
dc.identifier.issn0276-7333-
dc.identifier.urihttp://hdl.handle.net/10722/237575-
dc.description.abstractThe unusual heterovalent bimetallic Ni1-Ni0 complex {[η-C5H4CH=N(C6F5)]Fe[η- C5H4PPh2]}2Ni2(Cl) (2) was isolated from the reaction between [η-C5H4CH= N(C6F5)]Fe[η-C5H4PPh 2] (1) and Ni(COD)2 in the presence of AlEtCl2 or AlCl3. Complex 2 has been crystallographically characterized and theoretically analyzed; it is catalytically active (TOF 90 500) and selective (91%) toward the formation of C4 oligomers from ethylene (300 psi) at 30 °C, the only other significant isomer formed being C6. © 2007 American Chemical Society.-
dc.languageeng-
dc.relation.ispartofOrganometallics-
dc.titleA strange nickel(I)-nickel(0) binuclear complex and its unexpected ethylene oligomerization-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1021/om0701322-
dc.identifier.scopuseid_2-s2.0-34250747836-
dc.identifier.volume26-
dc.identifier.issue12-
dc.identifier.spage2950-
dc.identifier.epage2952-
dc.identifier.isiWOS:000246764400002-

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