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Article: Formation and structures of Pd(II) N,S-heterocyclic carbene-pyridyl mixed-ligand complexes
Title | Formation and structures of Pd(II) N,S-heterocyclic carbene-pyridyl mixed-ligand complexes |
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Authors | |
Keywords | N,S-heterocyclic carbene Palladium Thiazolium Pyridyl Anagostic |
Issue Date | 2009 |
Citation | Journal of Organometallic Chemistry, 2009, v. 694, n. 3, p. 332-338 How to Cite? |
Abstract | Mononuclear mixed-ligand complexes of Pd(II) containing a N,S-heterocyclic carbene (NSHC) with a secondary alkyl N-substituent and pyridyl ligand, with the general formula [PdI2(C10H11NS)L] (C10H11NS = 3-isopropylbenzothiazolin-2-ylidene; L = pyridine, 2-aminopyridine, 3-iodopyridine and 4-tert-butyl-pyridine) have been synthesized and characterized by X-ray single-crystal crystallography. Both solution and solid-state structures, as evident from their 1H NMR spectra and X-ray structures, show anagostic γ-hydrogen interactions of metal with methine of the substituent on the carbene or pyridyl ligand giving 5-membered-chelate-like structures. © 2008. |
Persistent Identifier | http://hdl.handle.net/10722/237589 |
ISSN | 2023 Impact Factor: 2.1 2023 SCImago Journal Rankings: 0.359 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Yen, Swee Kuan | - |
dc.contributor.author | Koh, Lip Lin | - |
dc.contributor.author | Huynh, Han Vinh | - |
dc.contributor.author | Andy Hor, T. S. | - |
dc.date.accessioned | 2017-01-16T06:10:00Z | - |
dc.date.available | 2017-01-16T06:10:00Z | - |
dc.date.issued | 2009 | - |
dc.identifier.citation | Journal of Organometallic Chemistry, 2009, v. 694, n. 3, p. 332-338 | - |
dc.identifier.issn | 0022-328X | - |
dc.identifier.uri | http://hdl.handle.net/10722/237589 | - |
dc.description.abstract | Mononuclear mixed-ligand complexes of Pd(II) containing a N,S-heterocyclic carbene (NSHC) with a secondary alkyl N-substituent and pyridyl ligand, with the general formula [PdI2(C10H11NS)L] (C10H11NS = 3-isopropylbenzothiazolin-2-ylidene; L = pyridine, 2-aminopyridine, 3-iodopyridine and 4-tert-butyl-pyridine) have been synthesized and characterized by X-ray single-crystal crystallography. Both solution and solid-state structures, as evident from their 1H NMR spectra and X-ray structures, show anagostic γ-hydrogen interactions of metal with methine of the substituent on the carbene or pyridyl ligand giving 5-membered-chelate-like structures. © 2008. | - |
dc.language | eng | - |
dc.relation.ispartof | Journal of Organometallic Chemistry | - |
dc.subject | N,S-heterocyclic carbene | - |
dc.subject | Palladium | - |
dc.subject | Thiazolium | - |
dc.subject | Pyridyl | - |
dc.subject | Anagostic | - |
dc.title | Formation and structures of Pd(II) N,S-heterocyclic carbene-pyridyl mixed-ligand complexes | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1016/j.jorganchem.2008.10.048 | - |
dc.identifier.scopus | eid_2-s2.0-58249096372 | - |
dc.identifier.volume | 694 | - |
dc.identifier.issue | 3 | - |
dc.identifier.spage | 332 | - |
dc.identifier.epage | 338 | - |
dc.identifier.isi | WOS:000262608500004 | - |
dc.identifier.issnl | 0022-328X | - |