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Article: Intramolecular (4+3) Cycloadditions of Pyrroles and Application to the Synthesis of the Core of Class II Galbulimima Alkaloids

TitleIntramolecular (4+3) Cycloadditions of Pyrroles and Application to the Synthesis of the Core of Class II Galbulimima Alkaloids
Authors
Keywordsalkaloids
asymmetric synthesis
cycloaddition
epoxy enolsilanes
natural product synthesis
Issue Date2018
PublisherWiley - VCH Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home
Citation
Angewandte Chemie (International Edition), 2018, v. 57 n. 19, p. 5253-5256 How to Cite?
AbstractThe first intramolecular (4+3) cycloaddition of pyrroles with epoxy enolsilanes as the electrophiles was developed and used to generate optically-enriched cycloadducts containing the nortropane substructure in good yields. Using this pyrrole cycloaddition as the key step, we achieved the asymmetric synthesis of a nortropane compound bearing the BCDEF ring structure common to the Class II galbulimima alkaloids. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
Persistent Identifierhttp://hdl.handle.net/10722/251844
ISSN
2019 Impact Factor: 12.959
2015 SCImago Journal Rankings: 6.229
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorHe, J-
dc.contributor.authorChen, ZH-
dc.contributor.authorLi, WF-
dc.contributor.authorLow, KH-
dc.contributor.authorChiu, P-
dc.date.accessioned2018-03-19T07:02:07Z-
dc.date.available2018-03-19T07:02:07Z-
dc.date.issued2018-
dc.identifier.citationAngewandte Chemie (International Edition), 2018, v. 57 n. 19, p. 5253-5256-
dc.identifier.issn1433-7851-
dc.identifier.urihttp://hdl.handle.net/10722/251844-
dc.description.abstractThe first intramolecular (4+3) cycloaddition of pyrroles with epoxy enolsilanes as the electrophiles was developed and used to generate optically-enriched cycloadducts containing the nortropane substructure in good yields. Using this pyrrole cycloaddition as the key step, we achieved the asymmetric synthesis of a nortropane compound bearing the BCDEF ring structure common to the Class II galbulimima alkaloids. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim-
dc.languageeng-
dc.publisherWiley - VCH Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home-
dc.relation.ispartofAngewandte Chemie (International Edition)-
dc.subjectalkaloids-
dc.subjectasymmetric synthesis-
dc.subjectcycloaddition-
dc.subjectepoxy enolsilanes-
dc.subjectnatural product synthesis-
dc.titleIntramolecular (4+3) Cycloadditions of Pyrroles and Application to the Synthesis of the Core of Class II Galbulimima Alkaloids-
dc.typeArticle-
dc.identifier.emailLow, KH: khlow@hku.hk-
dc.identifier.emailChiu, P: pchiu@hku.hk-
dc.identifier.authorityChiu, P=rp00680-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/anie.201711439-
dc.identifier.pmid29493865-
dc.identifier.scopuseid_2-s2.0-85044870808-
dc.identifier.hkuros284582-
dc.identifier.volume57-
dc.identifier.issue19-
dc.identifier.spage5253-
dc.identifier.epage5256-
dc.identifier.isiWOS:000431035500007-
dc.publisher.placeGermany-

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