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Article: Excited State Dynamics of Isocyano Rhenium(I) Phenanthroline Complexes from Time‐Resolved Spectroscopy

TitleExcited State Dynamics of Isocyano Rhenium(I) Phenanthroline Complexes from Time‐Resolved Spectroscopy
Authors
Keywordsdensity functional calculations
isocyanide ligands
Raman spectroscopy
rhenium
time-resolved spectroscopy
Issue Date2019
PublisherWiley - V C H Verlag GmbH & Co KGaA. The Journal's web site is located at http://www.chemphyschem.com
Citation
ChemPhysChem, 2019, v. 20 n. 15, p. 1946-1953 How to Cite?
AbstractThe photophysical processes in a series of isocyano Re(I) phenanthroline complexes {[Re(CNR)n(CO)4‐n(phen)](PF6); n=2, 3, 4, R=2,6‐(iPr)2C6H3‐ or tBu‐ (n=2)} in acetonitrile have been studied by resonance Raman spectroscopy, transient resonance Raman spectroscopy, and femtosecond / nanosecond transient spectroscopy to elucidate the nature of their electronic transitions and emissive excited state(s). The kinetics of the intersystem crossing, vibrational relaxation and radiative decay of the metal‐to‐ligand charge transfer {MLCT [dπ(Re)→π*(phen)]} excited state have also been determined.
Persistent Identifierhttp://hdl.handle.net/10722/286178
ISSN
2020 Impact Factor: 3.102
2020 SCImago Journal Rankings: 1.016
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorCheng, SC-
dc.contributor.authorChu, WK-
dc.contributor.authorKo, CC-
dc.contributor.authorPhillips, DL-
dc.date.accessioned2020-08-31T07:00:14Z-
dc.date.available2020-08-31T07:00:14Z-
dc.date.issued2019-
dc.identifier.citationChemPhysChem, 2019, v. 20 n. 15, p. 1946-1953-
dc.identifier.issn1439-4235-
dc.identifier.urihttp://hdl.handle.net/10722/286178-
dc.description.abstractThe photophysical processes in a series of isocyano Re(I) phenanthroline complexes {[Re(CNR)n(CO)4‐n(phen)](PF6); n=2, 3, 4, R=2,6‐(iPr)2C6H3‐ or tBu‐ (n=2)} in acetonitrile have been studied by resonance Raman spectroscopy, transient resonance Raman spectroscopy, and femtosecond / nanosecond transient spectroscopy to elucidate the nature of their electronic transitions and emissive excited state(s). The kinetics of the intersystem crossing, vibrational relaxation and radiative decay of the metal‐to‐ligand charge transfer {MLCT [dπ(Re)→π*(phen)]} excited state have also been determined.-
dc.languageeng-
dc.publisherWiley - V C H Verlag GmbH & Co KGaA. The Journal's web site is located at http://www.chemphyschem.com-
dc.relation.ispartofChemPhysChem-
dc.rightsThis is the peer reviewed version of the following article: [FULL CITE], which has been published in final form at [Link to final article using the DOI]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.-
dc.subjectdensity functional calculations-
dc.subjectisocyanide ligands-
dc.subjectRaman spectroscopy-
dc.subjectrhenium-
dc.subjecttime-resolved spectroscopy-
dc.titleExcited State Dynamics of Isocyano Rhenium(I) Phenanthroline Complexes from Time‐Resolved Spectroscopy-
dc.typeArticle-
dc.identifier.emailPhillips, DL: phillips@hku.hk-
dc.identifier.authorityPhillips, DL=rp00770-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/cphc.201900581-
dc.identifier.pmid31231907-
dc.identifier.scopuseid_2-s2.0-85068924830-
dc.identifier.hkuros313840-
dc.identifier.volume20-
dc.identifier.issue15-
dc.identifier.spage1946-
dc.identifier.epage1953-
dc.identifier.isiWOS:000474991600001-
dc.publisher.placeGermany-
dc.identifier.issnl1439-4235-

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