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- Publisher Website: 10.1039/D0CC05340F
- Scopus: eid_2-s2.0-85092233604
- PMID: 32909558
- WOS: WOS:000575366000037
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Article: Synthesis of P-chiral phosphine compounds by palladium-catalyzed C–P coupling reactions
Title | Synthesis of P-chiral phosphine compounds by palladium-catalyzed C–P coupling reactions |
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Authors | |
Issue Date | 2020 |
Publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp |
Citation | Chemical Communications, 2020, v. 56 n. 79, p. 11775-11778 How to Cite? |
Abstract | An efficient C–P coupling reaction of enantiopure tert-butylmethylphosphine-boranes with aryl and heteroaryl halides is developed by using Pd(OAc)2/dppf as a catalyst, affording a series of (S) or (R)-P-chiral phosphines in moderate to high yields and with ee values up to 99% ee. Moreover, the reaction time could be reduced from 72 h to 6 h with increased ee values under microwave irradiation. |
Persistent Identifier | http://hdl.handle.net/10722/302451 |
ISSN | 2023 Impact Factor: 4.3 2023 SCImago Journal Rankings: 1.133 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Wang, C | - |
dc.contributor.author | Yue, CD | - |
dc.contributor.author | Yuan, J | - |
dc.contributor.author | Zheng, JL | - |
dc.contributor.author | Zhang, Y | - |
dc.contributor.author | Yu, H | - |
dc.contributor.author | Chen, J | - |
dc.contributor.author | Meng, S | - |
dc.contributor.author | Yu, Y | - |
dc.contributor.author | Yu, GA | - |
dc.contributor.author | Che, CM | - |
dc.date.accessioned | 2021-09-06T03:32:29Z | - |
dc.date.available | 2021-09-06T03:32:29Z | - |
dc.date.issued | 2020 | - |
dc.identifier.citation | Chemical Communications, 2020, v. 56 n. 79, p. 11775-11778 | - |
dc.identifier.issn | 1359-7345 | - |
dc.identifier.uri | http://hdl.handle.net/10722/302451 | - |
dc.description.abstract | An efficient C–P coupling reaction of enantiopure tert-butylmethylphosphine-boranes with aryl and heteroaryl halides is developed by using Pd(OAc)2/dppf as a catalyst, affording a series of (S) or (R)-P-chiral phosphines in moderate to high yields and with ee values up to 99% ee. Moreover, the reaction time could be reduced from 72 h to 6 h with increased ee values under microwave irradiation. | - |
dc.language | eng | - |
dc.publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp | - |
dc.relation.ispartof | Chemical Communications | - |
dc.title | Synthesis of P-chiral phosphine compounds by palladium-catalyzed C–P coupling reactions | - |
dc.type | Article | - |
dc.identifier.email | Che, CM: chemhead@hku.hk | - |
dc.identifier.authority | Che, CM=rp00670 | - |
dc.description.nature | postprint | - |
dc.identifier.doi | 10.1039/D0CC05340F | - |
dc.identifier.pmid | 32909558 | - |
dc.identifier.scopus | eid_2-s2.0-85092233604 | - |
dc.identifier.hkuros | 324863 | - |
dc.identifier.volume | 56 | - |
dc.identifier.issue | 79 | - |
dc.identifier.spage | 11775 | - |
dc.identifier.epage | 11778 | - |
dc.identifier.isi | WOS:000575366000037 | - |
dc.publisher.place | United Kingdom | - |