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Article: Second Sphere Coordination of Cationic Rhodium Complexes by Dibenzo[3n]crown‐n Ethers

TitleSecond Sphere Coordination of Cationic Rhodium Complexes by Dibenzo[3n]crown‐n Ethers
Authors
Colquhoun, Howard M.Doughty, Simon M.Stoddart, J. FraserWilliams, David J.
Issue Date1984
Citation
Angewandte Chemie International Edition in English, 1984, v. 23, n. 3, p. 235-236 How to Cite?
DOI: http://dx.doi.org/10.1002/anie.198402351
AbstractAn unexpected spatial arrangement of the ligands has been observed in the 1 : 1 complexes of [Rh(L)(NH3)2]⊕ with dibenzo[24]crown‐8 as well as dibenzo[30]crown‐10 (L = cyclooctadiene or norbornadiene). The ligands are sandwiched between the two benzene rings of the receptor molecule. The stabilization presumably arise, above all, from [NH…O] hydrogen bonding and other electrostatic interactions. (Figure Presented.) Copyright © 1984 by Verlag Chemie, GmbH, Germany
Persistent Identifierhttp://hdl.handle.net/10722/333206
ISSN
0570-0833
ISI Accession Number ID
WOS:A1984SP25200010

 

DC FieldValueLanguage
dc.contributor.authorColquhoun, Howard M.-
dc.contributor.authorDoughty, Simon M.-
dc.contributor.authorStoddart, J. Fraser-
dc.contributor.authorWilliams, David J.-
dc.date.accessioned2023-10-06T05:17:31Z-
dc.date.available2023-10-06T05:17:31Z-
dc.date.issued1984-
dc.identifier.citationAngewandte Chemie International Edition in English, 1984, v. 23, n. 3, p. 235-236-
dc.identifier.issn0570-0833-
dc.identifier.urihttp://hdl.handle.net/10722/333206-
dc.description.abstractAn unexpected spatial arrangement of the ligands has been observed in the 1 : 1 complexes of [Rh(L)(NH3)2]⊕ with dibenzo[24]crown‐8 as well as dibenzo[30]crown‐10 (L = cyclooctadiene or norbornadiene). The ligands are sandwiched between the two benzene rings of the receptor molecule. The stabilization presumably arise, above all, from [NH…O] hydrogen bonding and other electrostatic interactions. (Figure Presented.) Copyright © 1984 by Verlag Chemie, GmbH, Germany-
dc.languageeng-
dc.relation.ispartofAngewandte Chemie International Edition in English-
dc.titleSecond Sphere Coordination of Cationic Rhodium Complexes by Dibenzo[3n]crown‐n Ethers-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/anie.198402351-
dc.identifier.scopuseid_2-s2.0-84985524329-
dc.identifier.volume23-
dc.identifier.issue3-
dc.identifier.spage235-
dc.identifier.epage236-
dc.identifier.eissn1521-3773-
dc.identifier.isiWOS:A1984SP25200010-

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