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Conference Paper: Through-space interactions in enshrouded m-terphenylsilanes

TitleThrough-space interactions in enshrouded m-terphenylsilanes
Authors
Romanato, PaolaDuttwyler, SimonLinden, AnthonyBaldridge, Kim K.Siegel, Jay S.
KeywordsCLAFQO
Physical organic
Issue Date2014
Citation
Journal of Physical Organic Chemistry, 2014, v. 27, n. 4, p. 277-283 How to Cite?
DOI: http://dx.doi.org/10.1002/poc.3265
AbstractA series of m-terphenyl-substituted silanes was prepared and studied with regard to the steric and electronic interactions between the silyl core and the terphenyl shroud. Only weak conformational preferences were observed for the core, but the π-basicity of the lateral rings led to distinct nuclear magnetic resonance shifts, and o-fluorine atoms led to through-space coupling effects. © 2014 John Wiley & Sons, Ltd.
Persistent Identifierhttp://hdl.handle.net/10722/341152
ISSN
0894-3230
2021 Impact Factor: 2.155
2020 SCImago Journal Rankings: 0.325
ISI Accession Number ID
WOS:000333469800007

 

DC FieldValueLanguage
dc.contributor.authorRomanato, Paola-
dc.contributor.authorDuttwyler, Simon-
dc.contributor.authorLinden, Anthony-
dc.contributor.authorBaldridge, Kim K.-
dc.contributor.authorSiegel, Jay S.-
dc.date.accessioned2024-03-13T08:40:34Z-
dc.date.available2024-03-13T08:40:34Z-
dc.date.issued2014-
dc.identifier.citationJournal of Physical Organic Chemistry, 2014, v. 27, n. 4, p. 277-283-
dc.identifier.issn0894-3230-
dc.identifier.urihttp://hdl.handle.net/10722/341152-
dc.description.abstractA series of m-terphenyl-substituted silanes was prepared and studied with regard to the steric and electronic interactions between the silyl core and the terphenyl shroud. Only weak conformational preferences were observed for the core, but the π-basicity of the lateral rings led to distinct nuclear magnetic resonance shifts, and o-fluorine atoms led to through-space coupling effects. © 2014 John Wiley & Sons, Ltd.-
dc.languageeng-
dc.relation.ispartofJournal of Physical Organic Chemistry-
dc.subjectCLAFQO-
dc.subjectPhysical organic-
dc.titleThrough-space interactions in enshrouded m-terphenylsilanes-
dc.typeConference_Paper-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/poc.3265-
dc.identifier.scopuseid_2-s2.0-84897914262-
dc.identifier.volume27-
dc.identifier.issue4-
dc.identifier.spage277-
dc.identifier.epage283-
dc.identifier.eissn1099-1395-
dc.identifier.isiWOS:000333469800007-

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