File Download
There are no files associated with this item.
Links for fulltext
(May Require Subscription)
- Publisher Website: 10.1021/cg800869u
- Scopus: eid_2-s2.0-65249155869
- WOS: WOS:000263921300037
- Find via
Supplementary
- Citations:
- Appears in Collections:
Article: Flexible thioether-Ag(I) interactions for assembling large organic ligands into crystalline networks
Title | Flexible thioether-Ag(I) interactions for assembling large organic ligands into crystalline networks | ||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|
Authors | |||||||||||
Issue Date | 2009 | ||||||||||
Publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/crystal | ||||||||||
Citation | Crystal Growth And Design, 2009, v. 9 n. 3, p. 1444-1451 How to Cite? | ||||||||||
Abstract | From searching the Cambridge Structural Database (CSD), we noticed an exceptionally widespread distribution of the interatomic distances (from 2.39 to 3.52 Å) between thioether S atoms and Ag(I) ions, in comparison with the cases in other common ligands such as nitriles and pyridyls. The variable bonding distances point to a highly flexible and reversible nature of thioether-Ag(I) interaction, which might help crystallize large and complex organic molecules into ordered coordination networks under mild conditions. We provide a number of new structures for illustration. In 1, two Ag(I) ions are coordinated by three 1,2,3- tris(methylthio)phenyl groups (i.e., 9 S atoms) to form a three-bladed paddlewheel block as a node for an enlarged honeycomb sheet. In 2, a porphyrin molecule with four l,2,3-tris(phenylthio)phenyl groups coordinates to Ag(I) atoms to form a parallelogram net, featuring free-standing phenylthio groups in the channel. In 3, a starburst molecule with six 4-methylthiophenyl groups attached to the triphenylene core is crystallized with AgOTf (triflate) to form a complex three-dimensional net, with a supramolecular topology featuring a combination of edge-sharing octahedra (the rutile chain) and vertex-sharing octahedra (the ReO 3 chain). © 2009 American Chemical Society. | ||||||||||
Persistent Identifier | http://hdl.handle.net/10722/58373 | ||||||||||
ISSN | 2023 Impact Factor: 3.2 2023 SCImago Journal Rankings: 0.649 | ||||||||||
ISI Accession Number ID |
Funding Information: This work is supported by a grant from the Research Grants Council of the Hong Kong Special Administrative Region, China [Project No. 9041212 (CityU 103407)]. The diffractometer was funded by NSF Grant 0087210, by the Ohio Board of Regents grant CAP-491, and by YSU. | ||||||||||
References |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Huang, G | en_HK |
dc.contributor.author | Tsang, CK | en_HK |
dc.contributor.author | Xu, Z | en_HK |
dc.contributor.author | Li, K | en_HK |
dc.contributor.author | Zeller, M | en_HK |
dc.contributor.author | Hunter, AD | en_HK |
dc.contributor.author | Chui, SSY | en_HK |
dc.contributor.author | Che, CM | en_HK |
dc.date.accessioned | 2010-05-31T03:29:10Z | - |
dc.date.available | 2010-05-31T03:29:10Z | - |
dc.date.issued | 2009 | en_HK |
dc.identifier.citation | Crystal Growth And Design, 2009, v. 9 n. 3, p. 1444-1451 | en_HK |
dc.identifier.issn | 1528-7483 | en_HK |
dc.identifier.uri | http://hdl.handle.net/10722/58373 | - |
dc.description.abstract | From searching the Cambridge Structural Database (CSD), we noticed an exceptionally widespread distribution of the interatomic distances (from 2.39 to 3.52 Å) between thioether S atoms and Ag(I) ions, in comparison with the cases in other common ligands such as nitriles and pyridyls. The variable bonding distances point to a highly flexible and reversible nature of thioether-Ag(I) interaction, which might help crystallize large and complex organic molecules into ordered coordination networks under mild conditions. We provide a number of new structures for illustration. In 1, two Ag(I) ions are coordinated by three 1,2,3- tris(methylthio)phenyl groups (i.e., 9 S atoms) to form a three-bladed paddlewheel block as a node for an enlarged honeycomb sheet. In 2, a porphyrin molecule with four l,2,3-tris(phenylthio)phenyl groups coordinates to Ag(I) atoms to form a parallelogram net, featuring free-standing phenylthio groups in the channel. In 3, a starburst molecule with six 4-methylthiophenyl groups attached to the triphenylene core is crystallized with AgOTf (triflate) to form a complex three-dimensional net, with a supramolecular topology featuring a combination of edge-sharing octahedra (the rutile chain) and vertex-sharing octahedra (the ReO 3 chain). © 2009 American Chemical Society. | en_HK |
dc.language | eng | en_HK |
dc.publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/crystal | en_HK |
dc.relation.ispartof | Crystal Growth and Design | en_HK |
dc.title | Flexible thioether-Ag(I) interactions for assembling large organic ligands into crystalline networks | en_HK |
dc.type | Article | en_HK |
dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1528-7483&volume=9&spage=1444&epage=1451&date=2009&atitle=Flexible+Thioether-Ag(I)+Interactions+for+Assembling+Large+Organic+Ligands+into+Crystalline+Networks | en_HK |
dc.identifier.email | Chui, SSY: chuissy@hkucc.hku.hk | en_HK |
dc.identifier.email | Che, CM: cmche@hku.hk | en_HK |
dc.identifier.authority | Chui, SSY=rp00686 | en_HK |
dc.identifier.authority | Che, CM=rp00670 | en_HK |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1021/cg800869u | en_HK |
dc.identifier.scopus | eid_2-s2.0-65249155869 | en_HK |
dc.identifier.hkuros | 156010 | en_HK |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-65249155869&selection=ref&src=s&origin=recordpage | en_HK |
dc.identifier.volume | 9 | en_HK |
dc.identifier.issue | 3 | en_HK |
dc.identifier.spage | 1444 | en_HK |
dc.identifier.epage | 1451 | en_HK |
dc.identifier.isi | WOS:000263921300037 | - |
dc.publisher.place | United States | en_HK |
dc.identifier.scopusauthorid | Huang, G=36984730800 | en_HK |
dc.identifier.scopusauthorid | Tsang, CK=25032030900 | en_HK |
dc.identifier.scopusauthorid | Xu, Z=9843801700 | en_HK |
dc.identifier.scopusauthorid | Li, K=55487992100 | en_HK |
dc.identifier.scopusauthorid | Zeller, M=8518298000 | en_HK |
dc.identifier.scopusauthorid | Hunter, AD=7402779700 | en_HK |
dc.identifier.scopusauthorid | Chui, SSY=8297453100 | en_HK |
dc.identifier.scopusauthorid | Che, CM=7102442791 | en_HK |
dc.identifier.issnl | 1528-7483 | - |