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Article: Luminescent tetranuclear copper(I) and silver(I) chalcogenides

TitleLuminescent tetranuclear copper(I) and silver(I) chalcogenides
Authors
Yam, VWWLo, KKW
KeywordsBack-electron-transfer
Chalcogenides
Copper(I)
Intervalence-transfer transition
Ligand-to-metal charge-transfer transition
Luminescence
Mixed-valence
Oxidative quenching
Silver(I)
Tetranuclear
Issue Date1997
PublisherTaylor & Francis Inc. The Journal's web site is located at http://www.tandf.co.uk/journals/titles/02603594.asp
Citation
Comments On Inorganic Chemistry, 1997, v. 19 n. 4, p. 209-229 How to Cite?
DOI: http://dx.doi.org/10.1080/02603599708032737
AbstractA series of luminescent tetranuclear copper(I) and silver(I) chalcogenide complexes have been synthesized and characterized. The photophysical and photochemical properties of these complexes have also been investigated. The long-lived excited state of these luminescent clusters is believed to bear a high parentage of ligand-to-metal charge-transfer LMCT (E2- → M4) character. The assignment has also been supported by molecular orbital calculations.
Persistent Identifierhttp://hdl.handle.net/10722/70487
ISSN
0260-3594
2021 Impact Factor: 5.476
2020 SCImago Journal Rankings: 1.055
ISI Accession Number ID
WOS:000071460300001
References
References in Scopus

 

DC FieldValueLanguage
dc.contributor.authorYam, VWWen_HK
dc.contributor.authorLo, KKWen_HK
dc.date.accessioned2010-09-06T06:23:20Z-
dc.date.available2010-09-06T06:23:20Z-
dc.date.issued1997en_HK
dc.identifier.citationComments On Inorganic Chemistry, 1997, v. 19 n. 4, p. 209-229en_HK
dc.identifier.issn0260-3594en_HK
dc.identifier.urihttp://hdl.handle.net/10722/70487-
dc.description.abstractA series of luminescent tetranuclear copper(I) and silver(I) chalcogenide complexes have been synthesized and characterized. The photophysical and photochemical properties of these complexes have also been investigated. The long-lived excited state of these luminescent clusters is believed to bear a high parentage of ligand-to-metal charge-transfer LMCT (E2- → M4) character. The assignment has also been supported by molecular orbital calculations.en_HK
dc.languageengen_HK
dc.publisherTaylor & Francis Inc. The Journal's web site is located at http://www.tandf.co.uk/journals/titles/02603594.aspen_HK
dc.relation.ispartofComments on Inorganic Chemistryen_HK
dc.subjectBack-electron-transferen_HK
dc.subjectChalcogenidesen_HK
dc.subjectCopper(I)en_HK
dc.subjectIntervalence-transfer transitionen_HK
dc.subjectLigand-to-metal charge-transfer transitionen_HK
dc.subjectLuminescenceen_HK
dc.subjectMixed-valenceen_HK
dc.subjectOxidative quenchingen_HK
dc.subjectSilver(I)en_HK
dc.subjectTetranuclearen_HK
dc.titleLuminescent tetranuclear copper(I) and silver(I) chalcogenidesen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0020-1669&volume=19&issue=4&spage=209&epage=229&date=1997&atitle=Luminescent+tetranuclear+copper(I)+and+silver(I)+chalcogenidesen_HK
dc.identifier.emailYam, VWW:wwyam@hku.hken_HK
dc.identifier.authorityYam, VWW=rp00822en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1080/02603599708032737-
dc.identifier.scopuseid_2-s2.0-0031498284en_HK
dc.identifier.hkuros31399en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0031498284&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume19en_HK
dc.identifier.issue4en_HK
dc.identifier.spage209en_HK
dc.identifier.epage229en_HK
dc.identifier.isiWOS:000071460300001-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridYam, VWW=18539304700en_HK
dc.identifier.scopusauthoridLo, KKW=26032181200en_HK
dc.identifier.issnl0260-3594-

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