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- Publisher Website: 10.1016/j.jorganchem.2011.04.031
- Scopus: eid_2-s2.0-79960106122
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Conference Paper: Ferrocenyl iminophosphine ligands in Pd-catalysed Suzuki couplings
| Title | Ferrocenyl iminophosphine ligands in Pd-catalysed Suzuki couplings |
|---|---|
| Authors | |
| Keywords | Ferrocenyl Suzuki cross-coupling Phosphine Palladium |
| Issue Date | 2011 |
| Citation | Journal of Organometallic Chemistry, 2011, v. 696, n. 17, p. 2928-2934 How to Cite? |
| Abstract | A mixture of Pd2(dba)3/{η-C5H 4CHN[CH(CH3)(Nap)]}Fe[η-C5H 4P(tBu)2] efficiently catalyzes the Suzuki reactions of a variety of bulky aryl halides and aryl- and alkyl-boronic acids, affording the desired cross-coupling biaryl products in quantitative isolated yields under mild conditions and at low (1 × 10-6-1 mol%) Pd loadings. Spectroscopic (NMR & ESI) analysis of the mixture of Pd 2(dba)3, the hybrid [P,N] ligands, and aryl halides revealed different structural forms of oxidative addition products that are dependent on the substituent on the imino nitrogen. © 2011 Elsevier B.V. All rights reserved. |
| Persistent Identifier | http://hdl.handle.net/10722/219378 |
| ISSN | 2021 Impact Factor: 2.345 2020 SCImago Journal Rankings: 0.484 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Teo, Shihui | - |
| dc.contributor.author | Weng, Zhiqiang | - |
| dc.contributor.author | Hor, T. S Andy | - |
| dc.date.accessioned | 2015-09-23T02:56:55Z | - |
| dc.date.available | 2015-09-23T02:56:55Z | - |
| dc.date.issued | 2011 | - |
| dc.identifier.citation | Journal of Organometallic Chemistry, 2011, v. 696, n. 17, p. 2928-2934 | - |
| dc.identifier.issn | 0022-328X | - |
| dc.identifier.uri | http://hdl.handle.net/10722/219378 | - |
| dc.description.abstract | A mixture of Pd2(dba)3/{η-C5H 4CHN[CH(CH3)(Nap)]}Fe[η-C5H 4P(tBu)2] efficiently catalyzes the Suzuki reactions of a variety of bulky aryl halides and aryl- and alkyl-boronic acids, affording the desired cross-coupling biaryl products in quantitative isolated yields under mild conditions and at low (1 × 10-6-1 mol%) Pd loadings. Spectroscopic (NMR & ESI) analysis of the mixture of Pd 2(dba)3, the hybrid [P,N] ligands, and aryl halides revealed different structural forms of oxidative addition products that are dependent on the substituent on the imino nitrogen. © 2011 Elsevier B.V. All rights reserved. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Journal of Organometallic Chemistry | - |
| dc.subject | Ferrocenyl | - |
| dc.subject | Suzuki cross-coupling | - |
| dc.subject | Phosphine | - |
| dc.subject | Palladium | - |
| dc.title | Ferrocenyl iminophosphine ligands in Pd-catalysed Suzuki couplings | - |
| dc.type | Conference_Paper | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1016/j.jorganchem.2011.04.031 | - |
| dc.identifier.scopus | eid_2-s2.0-79960106122 | - |
| dc.identifier.volume | 696 | - |
| dc.identifier.issue | 17 | - |
| dc.identifier.spage | 2928 | - |
| dc.identifier.epage | 2934 | - |
| dc.identifier.isi | WOS:000292496000012 | - |
| dc.identifier.issnl | 0022-328X | - |