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Conference Paper: Dinuclear Cu(ii) 1,2,3-Triazole-Bridged Complex with Ferromagnetic Coupling
| Title | Dinuclear Cu(ii) 1,2,3-Triazole-Bridged Complex with Ferromagnetic Coupling |
|---|---|
| Authors | |
| Issue Date | 2013 |
| Citation | Australian Journal of Chemistry, 2013, v. 66, n. 9, p. 1029-1033 How to Cite? |
| Abstract | A new dinuclear Cu(ii) complex [Cu2Cl4(L1) 2] (1) (L1≤1-(2-picolyl)-4-hexyl-1H-1,2,3-triazole) has been synthesised and characterised by single-crystal X-ray diffraction (XRD) and powder XRD, thermogravimetric analysis, electron paramagnetic resonance spectrum, photoluminescence, and magnetic measurements. Complex 1 shows double 1,2,3-triazoles bridging the dinuclear Cu2N4 moiety, in which the bridging N≤N bond indicates basal-apical asymmetric mode with 112.6° torsion angle of Cu-N≤N-Cu. Different from most azole-bridged dinuclear Cu(ii) with antiferromagnetic couplings, complex 1 shows an intramolecular weak ferromagnetic interaction (J≤0.91cm-1). © 2013 CSIRO. |
| Persistent Identifier | http://hdl.handle.net/10722/219714 |
| ISSN | 2021 Impact Factor: 1.224 2020 SCImago Journal Rankings: 0.319 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Bai, Shi Qiang | - |
| dc.contributor.author | Jiang, Lu | - |
| dc.contributor.author | Zuo, Jing Lin | - |
| dc.contributor.author | Yan, Chun Hua | - |
| dc.contributor.author | Hor, T. S Andy | - |
| dc.date.accessioned | 2015-09-23T02:57:47Z | - |
| dc.date.available | 2015-09-23T02:57:47Z | - |
| dc.date.issued | 2013 | - |
| dc.identifier.citation | Australian Journal of Chemistry, 2013, v. 66, n. 9, p. 1029-1033 | - |
| dc.identifier.issn | 0004-9425 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/219714 | - |
| dc.description.abstract | A new dinuclear Cu(ii) complex [Cu2Cl4(L1) 2] (1) (L1≤1-(2-picolyl)-4-hexyl-1H-1,2,3-triazole) has been synthesised and characterised by single-crystal X-ray diffraction (XRD) and powder XRD, thermogravimetric analysis, electron paramagnetic resonance spectrum, photoluminescence, and magnetic measurements. Complex 1 shows double 1,2,3-triazoles bridging the dinuclear Cu2N4 moiety, in which the bridging N≤N bond indicates basal-apical asymmetric mode with 112.6° torsion angle of Cu-N≤N-Cu. Different from most azole-bridged dinuclear Cu(ii) with antiferromagnetic couplings, complex 1 shows an intramolecular weak ferromagnetic interaction (J≤0.91cm-1). © 2013 CSIRO. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Australian Journal of Chemistry | - |
| dc.title | Dinuclear Cu(ii) 1,2,3-Triazole-Bridged Complex with Ferromagnetic Coupling | - |
| dc.type | Conference_Paper | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1071/CH13224 | - |
| dc.identifier.scopus | eid_2-s2.0-84884177497 | - |
| dc.identifier.volume | 66 | - |
| dc.identifier.issue | 9 | - |
| dc.identifier.spage | 1029 | - |
| dc.identifier.epage | 1033 | - |
| dc.identifier.eissn | 1445-0038 | - |
| dc.identifier.isi | WOS:000324210400005 | - |
| dc.identifier.issnl | 0004-9425 | - |