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Article: Two distinct ferroceneyl carboxylate Pb(II) complexes with the same composition prepared by two different synthetic methods: The substitution of precursor and one-pot reaction

TitleTwo distinct ferroceneyl carboxylate Pb(II) complexes with the same composition prepared by two different synthetic methods: The substitution of precursor and one-pot reaction
Authors
Li, JinpengSong, ZhijiaLü, HuijuanHou, YongHou, HongweiFan, Yaoting
KeywordsCrystal structure
Electrochemical property
Lead
Precursor
Substitution reaction
Issue Date2010
Citation
Inorganic Chemistry Communications, 2010, v. 13, n. 3, p. 436-439 How to Cite?
DOI: http://dx.doi.org/10.1016/j.inoche.2010.01.006
AbstractThrough substituation reaction, one lead ferroceneyl carboxylate polymer, namely [Pb(μ2-OOCClH3C6Fc)2(phen)]n 1a [Fc = (η5-C5H5)Fe(η5-C5H4)] was synthesized from precursor [Pb(μ2-η2-OOCClH3C6Fc)2(CH3OH)2]n 1. However, a mononuclear Pb(II) complex {[Pb(η2-OOCClH3C6Fc)2(phen)]·(CH3OH)·(H2O)} 2 could be obtained from the traditional one-pot reaction of FcC6H3ClCOONa and Pb(OAc)2 with 1,10-phenantholine (phen). The electrochemical studies of 1, 1a, 2 and FcC6H3ClCOOH indicate that the half-wave potentials of the ferrocenyl moieties in these complexes are all shifted to positive potential compared with that of FcC6H3ClCOOH. © 2010 Elsevier B.V. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/367903
ISSN
1387-7003
2023 Impact Factor: 4.4
2023 SCImago Journal Rankings: 0.642

 

DC FieldValueLanguage
dc.contributor.authorLi, Jinpeng-
dc.contributor.authorSong, Zhijia-
dc.contributor.authorLü, Huijuan-
dc.contributor.authorHou, Yong-
dc.contributor.authorHou, Hongwei-
dc.contributor.authorFan, Yaoting-
dc.date.accessioned2025-12-19T08:00:15Z-
dc.date.available2025-12-19T08:00:15Z-
dc.date.issued2010-
dc.identifier.citationInorganic Chemistry Communications, 2010, v. 13, n. 3, p. 436-439-
dc.identifier.issn1387-7003-
dc.identifier.urihttp://hdl.handle.net/10722/367903-
dc.description.abstractThrough substituation reaction, one lead ferroceneyl carboxylate polymer, namely [Pb(μ<inf>2</inf>-OOCClH<inf>3</inf>C<inf>6</inf>Fc)<inf>2</inf>(phen)]<inf>n</inf> 1a [Fc = (η<sup>5</sup>-C<inf>5</inf>H<inf>5</inf>)Fe(η<sup>5</sup>-C<inf>5</inf>H<inf>4</inf>)] was synthesized from precursor [Pb(μ<inf>2</inf>-η<sup>2</sup>-OOCClH<inf>3</inf>C<inf>6</inf>Fc)<inf>2</inf>(CH<inf>3</inf>OH)<inf>2</inf>]<inf>n</inf> 1. However, a mononuclear Pb(II) complex {[Pb(η<sup>2</sup>-OOCClH<inf>3</inf>C<inf>6</inf>Fc)<inf>2</inf>(phen)]·(CH<inf>3</inf>OH)·(H<inf>2</inf>O)} 2 could be obtained from the traditional one-pot reaction of FcC<inf>6</inf>H<inf>3</inf>ClCOONa and Pb(OAc)<inf>2</inf> with 1,10-phenantholine (phen). The electrochemical studies of 1, 1a, 2 and FcC<inf>6</inf>H<inf>3</inf>ClCOOH indicate that the half-wave potentials of the ferrocenyl moieties in these complexes are all shifted to positive potential compared with that of FcC<inf>6</inf>H<inf>3</inf>ClCOOH. © 2010 Elsevier B.V. All rights reserved.-
dc.languageeng-
dc.relation.ispartofInorganic Chemistry Communications-
dc.subjectCrystal structure-
dc.subjectElectrochemical property-
dc.subjectLead-
dc.subjectPrecursor-
dc.subjectSubstitution reaction-
dc.titleTwo distinct ferroceneyl carboxylate Pb(II) complexes with the same composition prepared by two different synthetic methods: The substitution of precursor and one-pot reaction-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/j.inoche.2010.01.006-
dc.identifier.scopuseid_2-s2.0-76749117955-
dc.identifier.volume13-
dc.identifier.issue3-
dc.identifier.spage436-
dc.identifier.epage439-

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